Conformational transmission in nucleotides containing trigonal bipyramidal phosphorus as the internucleoside linkage

LH Koole, MHP Van Genderen…

Index: Koole, Leo H.; Genderen, Marcel H. P. van; Buck, Henk M. Journal of Organic Chemistry, 1988 , vol. 53, # 22 p. 5266 - 5272

Full Text: HTML

Citation Number: 7

Abstract

A set of nucleotide analogues containing a stable trigonal bipyramidal phosphorus (Pv TBP) moiety (5-1 1) has been developed, and their conformational properties were studied with 300-and 500-MHz 'H NMR. In the solvent acetone-d,, it is found that the conformation of ...