Solvent-free synthesis of aryl ethers promoted by tetrabutylammonium fluoride

W Xiong, Q Ding, J Chen, J Ding…

Index: Xiong, Wei; Ding, Quansheng; Chen, Jiuxi; Ding, Jinchang; Wu, Huayue Journal of Chemical Research, 2010 , # 7 p. 395 - 398

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Abstract

The reaction of aryl fluorides with silyl reagents has been shown to be efficiently promoted by tetrabutylammonium fluoride, providing aryl ethers with good to excellent yields under solvent-free conditions. The efficiency of this reaction was demonstrated by the compatibility with aldehyde, nitro, cyano and acetyl groups. Moreover, the rigorous exclusion of air/moisture was not required in these transformations which proceeded under milder ...

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