Monatshefte für Chemie/Chemical Monthly

Zur Kenntnis der gemeinsamen Einwirkung von elementarem Selen und gasförmigem Ammoniak bzw. Ethylenimin auf Ketone

F Asinger, MK Schmitz

Index: Asinger, Friedrich; Schmitz, Maria Karoline Monatshefte fuer Chemie, 1982 , vol. 113, p. 1191 - 1212

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Citation Number: 8

Abstract

Abstract Elemental sulfur reacts with ketones and gaseous ammonia at room temperature yielding thiazoline-3 in excellent yields. Under the same conditions elemental selenium does not react at all. Attempts using the known techniques which have been applied in improving the reactivity of slowly reacting ketones in thiazoline-3-synthesis have been unsuccessful (Exp. No. 1–17). The reaction of α-halogenketones with ...