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Monatshefte für Chemie/Chemical Monthly

Zur Kenntnis der gemeinsamen Einwirkung von elementarem Selen und gasförmigem Ammoniak bzw. Ethylenimin auf Ketone

F Asinger, MK Schmitz

文献索引:Asinger, Friedrich; Schmitz, Maria Karoline Monatshefte fuer Chemie, 1982 , vol. 113, p. 1191 - 1212

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被引用次数: 8

摘要

Abstract Elemental sulfur reacts with ketones and gaseous ammonia at room temperature yielding thiazoline-3 in excellent yields. Under the same conditions elemental selenium does not react at all. Attempts using the known techniques which have been applied in improving the reactivity of slowly reacting ketones in thiazoline-3-synthesis have been unsuccessful (Exp. No. 1–17). The reaction of α-halogenketones with ...