The Journal of organic chemistry

Synthesis of optically active vicinal fluorohydrins by lipase-catalyzed deracemization

D Wölker, G Haufe

Index: Pietz, Sylke; Woelker, Doerthe; Haufe, Guenter Tetrahedron, 1997 , vol. 53, # 50 p. 17067 - 17078

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Citation Number: 21

Abstract

Three microbial lipases have been used to deracemize trans-2-fluorocycloalkanols 2 both by hydrolysis of the corresponding acetates 3 or chloroacetates 4 and by esterification of the fluorohydrins 2 using vinyl acetate and vinyl chloroacetate, respectively. Pseudomonas

Enantioselektive Synthesen cyclopentanoider Verbindungen aus...

[Baldenius, Kai-U.; Dieck, Heindirk tom; Koenig, Wilfried A.; Icheln, Detlef; Runge, Torsten Angewandte Chemie, 1992 , vol. 104, # 3 p. 338 - 340]

Transannular π-cyclization in electrophilic additions to 1, ...

[Haufe, G.; Wolf, A.; Schulze, K. Tetrahedron, 1986 , vol. 42, # 17 p. 4719 - 4728]