Palladium-catalyzed Exchange of Allylic Groups of Ethers and Esters with Active Hydrogen Compounds. II.

K Takahashi, A Miyake, G Hata

Index: Takahashi,K. et al. Bulletin of the Chemical Society of Japan, 1972 , vol. 45, p. 230 - 236

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Citation Number: 131

Abstract

The allylic compounds (I), R 1–O–R (R= allylic groups, R 1= Ph, Me, PhCH 2, MeCO), react with active-hydrogen compounds such as phenols, alcohols, carboxylic acids, primary and secondary amines and active methylene compounds, to give allylic derivatives of the active- hydrogen compounds by an intermolecular exchange of the allylic groups of I with the atom to which the active hydrogens are bonded in the presence of palladium catalysts. Allyl and ...