e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Tetrahedron Letters

Fast oxidation of secondary alcohols by the bromate-bromide system using cyclic microwave heating in acidic water

S Pääkkönen, J Pursiainen, M Lajunen

Index: Tetrahedron Letters, , vol. 51, # 51 p. 6695 - 6699

Full Text: HTML

Citation Number: 16

Abstract

... Tetrahedron Letters. Volume 51, Issue 51, 22 December 2010, Pages 6695–6699. ... 24 In this Letter we report a cyclic microwave activation technique developed for this oxidation which led to a significant reduction in reaction time, increased yields, and a decrease in the amount ...

2-Hexanol Structure

~%

2-Hexanone Structure

3-BROMO 2-HEXANONE Structure

3-BROMO 2-HEXANONE

2-Hexanol Structure

~%

2-Hexanone Structure

1-bromo hexan-2-one Structure

1-bromo hexan-2-one

3-BROMO 2-HEXANONE Structure

3-BROMO 2-HEXANONE

3,3-dimethyl-2-butanol Structure

3,3-dimethyl-2-...

~%

Pinacolone Structure

1-Brom-3,3-dimethylbutan-2-on Structure

1-Brom-3,3-dime...

3,3-dimethyl-2-butanol Structure

3,3-dimethyl-2-...

~%

Pinacolone Structure

1-Brom-3,3-dimethylbutan-2-on Structure

1-Brom-3,3-dime...

(±)-2-Butanol Structure

~%

2-Butanone Structure

3-Bromo-2-butanone Structure

3-Bromo-2-butanone

(±)-2-Butanol Structure

~%

2-Butanone Structure

1-Bromo-2-butanone Structure

1-Bromo-2-butanone

3-Bromo-2-butanone Structure

3-Bromo-2-butanone

1-(4-Methylphenyl)ethanol Structure

1-(4-Methylphen...

~%

3'-Bromo-4'-methylacetophenone Structure

3'-Bromo-4'-met...

4'-Methylacetophenone Structure

4'-Methylacetop...

1-(4-Methylphenyl)ethanol Structure

1-(4-Methylphen...

~%

3'-Bromo-4'-methylacetophenone Structure

3'-Bromo-4'-met...

Benzenemethanol, 3-bromo-α,4-dimethyl- Structure

Benzenemethanol...

4'-Methylacetophenone Structure

4'-Methylacetop...

Detail

1-(4-Methylphenyl)ethanol Structure

1-(4-Methylphen...

~%

3'-Bromo-4'-methylacetophenone Structure

3'-Bromo-4'-met...

(±)-2-bromo-1-(4-methylphenyl)ethan-1-ol Structure

(±)-2-bromo-1-(...

4'-Methylacetophenone Structure

4'-Methylacetop...

Detail

1-(4-Methylphenyl)ethanol Structure

1-(4-Methylphen...

~%

3'-Bromo-4'-methylacetophenone Structure

3'-Bromo-4'-met...

Benzenemethanol, 3-bromo-α,4-dimethyl- Structure

Benzenemethanol...

(±)-2-bromo-1-(4-methylphenyl)ethan-1-ol Structure

(±)-2-bromo-1-(...

Detail

(±)-2-Butanol Structure

~%

2-Butanone Structure

1-Bromo-2-butanone Structure

1-Bromo-2-butanone

3-Bromo-2-butanone Structure

3-Bromo-2-butanone

(±)-2-Butanol Structure

~%

2-Butanone Structure

3-Bromo-2-butanone Structure

3-Bromo-2-butanone

(±)-2-Butanol Structure

~%

2-Butanone Structure

1-Bromo-2-butanone Structure

1-Bromo-2-butanone

3-Bromo-2-butanone Structure

3-Bromo-2-butanone

1-(4-Chlorophenyl)ethanol Structure

1-(4-Chlorophen...

~%

1-(4-Chlorophenyl)ethanone Structure

1-(4-Chlorophen...

2-Bromo-4'-chloroacetophenone Structure

2-Bromo-4'-chlo...

Methylbenzylalcohol Structure

Methylbenzylalcohol

~%

1-(4-Bromophenyl)ethanone Structure

1-(4-Bromopheny...

Acetophenone Structure

Methylbenzylalcohol Structure

Methylbenzylalcohol

~%

1-(4-Bromophenyl)ethanone Structure

1-(4-Bromopheny...

Acetophenone Structure

2-Bromoacetophenone Structure

2-Bromoacetophenone

Benzhydrol Structure

~%

Benzophenone Structure

4-Bromobenzophenone Structure

4-Bromobenzophenone

1-(4-Chlorophenyl)ethanol Structure

1-(4-Chlorophen...

~%

1-(4-Chlorophenyl)ethanone Structure

1-(4-Chlorophen...

2-Bromo-4'-chloroacetophenone Structure

2-Bromo-4'-chlo...

UNII:93FF0F303R Structure

UNII:93FF0F303R

~%

3-Methyl-2-butanone Structure

3-Methyl-2-butanone

2-Butanone,3-bromo-3-methyl- Structure

2-Butanone,3-br...

UNII:93FF0F303R Structure

UNII:93FF0F303R

~%

3-Methyl-2-butanone Structure

3-Methyl-2-butanone

2-Butanone,3-bromo-3-methyl- Structure

2-Butanone,3-br...

1-Bromo-3-methyl-2-butanone Structure

1-Bromo-3-methy...

1-(4-Methylphenyl)ethanol Structure

1-(4-Methylphen...

~%

3'-Bromo-4'-methylacetophenone Structure

3'-Bromo-4'-met...

4'-Methylacetophenone Structure

4'-Methylacetop...

1-(4-Methylphenyl)ethanol Structure

1-(4-Methylphen...

~%

3'-Bromo-4'-methylacetophenone Structure

3'-Bromo-4'-met...

Benzenemethanol, 3-bromo-α,4-dimethyl- Structure

Benzenemethanol...

4'-Methylacetophenone Structure

4'-Methylacetop...

Detail

1-(4-Methylphenyl)ethanol Structure

1-(4-Methylphen...

~%

3'-Bromo-4'-methylacetophenone Structure

3'-Bromo-4'-met...

(±)-2-bromo-1-(4-methylphenyl)ethan-1-ol Structure

(±)-2-bromo-1-(...

4'-Methylacetophenone Structure

4'-Methylacetop...

Detail

1-(4-Methylphenyl)ethanol Structure

1-(4-Methylphen...

~%

3'-Bromo-4'-methylacetophenone Structure

3'-Bromo-4'-met...

Benzenemethanol, 3-bromo-α,4-dimethyl- Structure

Benzenemethanol...

(±)-2-bromo-1-(4-methylphenyl)ethan-1-ol Structure

(±)-2-bromo-1-(...

Detail

1-(4-Methylphenyl)ethanol Structure

1-(4-Methylphen...

~%

3'-Bromo-4'-methylacetophenone Structure

3'-Bromo-4'-met...

Benzenemethanol, 3-bromo-α,4-dimethyl- Structure

Benzenemethanol...

4'-Methylacetophenone Structure

4'-Methylacetop...

Detail

1-(4-Methylphenyl)ethanol Structure

1-(4-Methylphen...

~%

3'-Bromo-4'-methylacetophenone Structure

3'-Bromo-4'-met...

(±)-2-bromo-1-(4-methylphenyl)ethan-1-ol Structure

(±)-2-bromo-1-(...

4'-Methylacetophenone Structure

4'-Methylacetop...

Detail

1-(4-Methylphenyl)ethanol Structure

1-(4-Methylphen...

~%

3'-Bromo-4'-methylacetophenone Structure

3'-Bromo-4'-met...

Benzenemethanol, 3-bromo-α,4-dimethyl- Structure

Benzenemethanol...

(±)-2-bromo-1-(4-methylphenyl)ethan-1-ol Structure

(±)-2-bromo-1-(...

Detail

Pentan-3-ol Structure

~%

3-Pentanone,2-bromo- Structure

3-Pentanone,2-bromo-

3-Pentanone Structure

Catalytic Conversions in Water. Part 23: Steric Effects and ...

[Ten Brink, Gerd-Jan; Arends, Isabel W. C. E.; Hoogenraad, Marcel; Verspui, Goeran; Sheldon, Roger A. Advanced Synthesis and Catalysis, 2003 , vol. 345, # 12 p. 1341 - 1352]

Highly Efficient AuI??Catalyzed Hydration of Alkynes

[Angewandte Chemie - International Edition, , vol. 41, # 23 p. 4563 - 4565]

Sustained epoxidation of olefins by oxygen donors catalyzed ...

[Journal of the American Chemical Society, , vol. 108, p. 536 - 538]

Reduction of ethylenic insaturations by in situ generated hy...

[Fort, Y.; Vanderesse, R.; Caubere, P. Chemistry Letters, 1988 , # 5 p. 757 - 760]

A Facile Procedure for the Conversion of Oximes to Ketones a...

[Lou, Ji-Dong; Lin, Fang; Lu, Xiu Lian; Wang, Qiang; Zou, Xiao-Nan Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2012 , vol. 42, # 2 p. 282 - 284]