氢化奎宁 1,4-(2,3-二氮杂萘)二醚结构式
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常用名 | 氢化奎宁 1,4-(2,3-二氮杂萘)二醚 | 英文名 | (DHQ)2PHAL |
|---|---|---|---|---|
| CAS号 | 140924-50-1 | 分子量 | 778.980 | |
| 密度 | 1.3±0.1 g/cm3 | 沸点 | N/A | |
| 分子式 | C48H54N6O4 | 熔点 | 178ºC (dec.) | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS07 |
信号词 | Warning |
氢化奎宁 1,4-(2,3-二氮杂萘)二醚用途【用途一】 配体，用于不饱和酯和三取代 C=C 键的非对称二羟基化。 |
| 中文名 | 氢化奎宁 1,4-(2,3-二氮杂萘)二醚 |
|---|---|
| 英文名 | 4-[(R)-[(2R,4S,5R)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxyquinolin-4-yl)methoxy]-1-[(R)-[(2R,4R,5S)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxyquinolin-4-yl)methoxy]phthalazine |
| 中文别名 | 氢化奎宁1,4-(2,3-二氮杂萘)二醚 (DHQ)2PHAL | 手性催化剂 | 氢化奎宁1,4-酞嗪二醚 | (DHQ)2PHAL 双羟化配体 |
| 英文别名 | 更多 |
| 密度 | 1.3±0.1 g/cm3 |
|---|---|
| 熔点 | 178ºC (dec.) |
| 分子式 | C48H54N6O4 |
| 分子量 | 778.980 |
| 精确质量 | 778.420654 |
| PSA | 94.96000 |
| LogP | 9.20 |
| 外观性状 | 固体;White to Light yellow powder to crystal |
| 折射率 | 1.688 |
| 储存条件 | 存放于惰性气体之中;避免空气 |
| 符号 |
GHS07 |
|---|---|
| 信号词 | Warning |
| 危害声明 | H317 |
| 警示性声明 | P280 |
| 个人防护装备 | Eyeshields;Faceshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
| 危害码 (欧洲) | Xi |
| 安全声明 (欧洲) | S22-S24/25 |
| 危险品运输编码 | NONH for all modes of transport |
| WGK德国 | 3 |
| 海关编码 | 2933990090 |
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氢化奎宁 1,4-(2,3-二... 140924-50-1 |
| 文献：Journal of Organic Chemistry, , vol. 57, # 10 p. 2768 - 2771 |
| 氢化奎宁 1,4-(2,3-二氮杂萘)二醚上游产品 2 | |
|---|---|
| 氢化奎宁 1,4-(2,3-二氮杂萘)二醚下游产品 0 | |
| 海关编码 | 2933990090 |
|---|---|
| 中文概述 | 2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0% |
| 申报要素 | 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期 |
| Summary | 2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |
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De novo synthesis of 2-substituted syn-1,3-diols via an iterative asymmetric hydration strategy.
J. Org. Chem. 71 , 7741, (2006) The enantioselective syntheses of several protected 4-substituted syn-3,5-dihydroxy carboxylic esters have been achieved from the corresponding achiral (E,E)- or (E,Z)-1,3-dienoates. The route relies ... |
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Kapferer, Tobias; Brueckner, Reinhard
European J. Org. Chem. 9 , 2119-2133, (2006)
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| (DHQ)2PHAL |
| MFCD00191975 |
| (8a,9R,8'''a,9'''R)-9,9'-[Phthalazine-1,4-diylbis(oxy)]bis(6'-methoxy-10,11-dihydrocinchonan) |
| (8α,9R,8'''α,9'''R)-9,9'-[1,4-Phthalazinediylbis(oxy)]bis(6'-methoxy-10,11-dihydrocinchonan) |
| Cinchonan, 9,9'-[1,4-phthalazinediylbis(oxy)]bis[10,11-dihydro-6'-methoxy-, (8α,9R,8'''α,9'''R)- |
| 4,5-Ethylenedithio-1,3-dithiol-2-one |
| (DHQ)PHAL |
| hydroquinine 1,4-phthalazinediyl diether |
| 5,6-dihydro-[1,2]dithiolo[4,5-b][1,4]dithiin-2-one |
| (8α,9R,8'''α,9'''R)-9,9'-[Phthalazine-1,4-diylbis(oxy)]bis(6'-methoxy-10,11-dihydrocinchonan) |
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