| 中文名 | 三苯基硫代锑酸盐 |
|---|---|
| 英文名 | triphenoxy(sulfanylidene)-λ5-stibane |
| 英文别名 |
Trithioantimonigsaeure-triphenylester
thiophenol,antimony tris-benzenethiolate Triphenyl trithioantimonite Thiophenol,Antimon-tris-benzenthiolat |
| 熔点 | 63-67 ℃ |
|---|---|
| 分子式 | C18H15S3Sb |
| 分子量 | 449.26700 |
| 精确质量 | 447.93700 |
| PSA | 75.90000 |
| LogP | 6.72900 |
| 分子结构 | 1、摩尔折射率：无可用 2、摩尔体积（cm3/mol）：无可用 3、等张比容（90.2K）：无可用 4、表面张力（dyne/cm）：无可用 5、极化率：无可用 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:4 4.可旋转化学键数量:6 5.互变异构体数量:无 6.拓扑分子极性表面积59.8 7.重原子数量:23 8.表面电荷:0 9.复杂度:329 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
Synonym:(Triphenylthio)antimon Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/22 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed.Harmful.The toxicological properties of this material have not been fully investigated.Stench.Moisture sensitive.Light sensitive.Air sensitive. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: Harmful if swallowed. Inhalation: Harmful if inhaled. May cause respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Do not store in direct sunlight. Store in a tightly closed container. Store in a dry area. Keep under a nitrogen blanket. Keep refrigerated. (Store below 4C/39F.) Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Limits CAS# 28609-58-7: United Kingdom, WEL - TWA: (listed as antimony): 0.5 mg/m3 TWA United Kingdom, WEL - STEL: (listed as antimony): 1.5 mg/m3 STEL United States OSHA: 0.5 mg/m3 TWA (listed under Antimony). Belgium - TWA: (listed as antimony): 0.5 mg/m3 VLE France - VME: (listed as antimony): 0.5 mg/m3 VME Germany: (listed as antimony): 0.5 mg/m3 VME Japan: (listed as antimony): 0.1 mg/m3 OEL Malaysia: (listed as antimony): 0.5 mg/m3 TWA Netherlands: (listed as antimony): 0.5 mg/m3 MAC Russia: (listed as antimony): 0.5 mg/m3 TWA Russia: (listed as antimony): 0.2 mg/m3 STEL Spain: (listed as antimony): 0.5 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron. Respirators: A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: yellow Odor: Stench. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 65 - 68 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C18H15S3Sb Molecular Weight: 449.35 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, light, exposure to air, exposure to moist air or water. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, oxides of sulfur, carbon dioxide, antimony/antimony oxides. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 28609-58-7 unlisted. LD50/LC50: Not available. Carcinogenicity: Triphenylthioantimonate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.* Hazard Class: 6.1 UN Number: 2811 Packing Group: III IMO Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing Group: III RID/ADR Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/22 Harmful by inhalation and if swallowed. Safety Phrases: S 22 Do not breathe dust. WGK (Water Danger/Protection) CAS# 28609-58-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 28609-58-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 28609-58-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。
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| 危害码 (欧洲) | F;Xn |
|---|---|
| 风险声明 (欧洲) | 51/53-20/22 |
| 安全声明 (欧洲) | 61 |