| 中文名 | 2,6-二仲丁基苯酚 |
|---|---|
| 英文名 | 2,6-di(butan-2-yl)phenol |
| 中文别名 | 双邻仲丁基酚 |
| 英文别名 |
2,6-Di-sec-butylphenol
UNII:862GFQ832E MFCD00009330 2,6-di(butan-2-yl)phenol 2,6-DI-SEC-BUTYL PHENOL Di-sec-butylphenol,mixed isomers Phenol, 2,6-bis(1-methylpropyl)- EINECS 226-854-6 PHENOL,2,6-DI-sec-BUTYL |
| 密度 | 0.9±0.1 g/cm3 |
|---|---|
| 沸点 | 257.5±0.0 °C at 760 mmHg |
| 熔点 | -42ºC |
| 分子式 | C14H22O |
| 分子量 | 206.324 |
| 闪点 | 127.4±7.2 °C |
| 精确质量 | 206.167068 |
| PSA | 20.23000 |
| LogP | 5.22 |
| 外观性状 | 琥珀色液体 |
| 蒸汽压 | 0.0±0.5 mmHg at 25°C |
| 折射率 | 1.507 |
| 稳定性 | 常温常压下稳定。与强氧化剂反应。 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:1 3.氢键受体数量:1 4.可旋转化学键数量:4 5.互变异构体数量:2 6.拓扑分子极性表面积20.2 7.重原子数量:15 8.表面电荷:0 9.复杂度:160 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:2 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：黄色透明液体 2. 密度（g/mL,25℃）：0.918 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：-42 5. 沸点（ºC,常压）：255-260 6. 沸点（ºC,0.5mmHg）：未确定 7. 折射率(n20/D)：1.508 8. 闪点（ºC）：127 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（mmHg,20ºC）：＜0.01 12. 饱和蒸气压（kPa,25ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
Synonym:2,6-Di-sec-butylfenol; Phenol, 2,6-bis (1-methylpropyl) Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Causes burns.Corrosive. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. Ingestion: May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes). Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 5510-99-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Amber Liquid Odor: None reported. pH: Not available. Vapor Pressure: < 0.1 mm Hg @ 20 C Viscosity: Not available. Boiling Point: 255.0 - 260.0 deg C @ 760.00m Freezing/Melting Point: -42 deg C Autoignition Temperature: Not available. Flash Point: 127 deg C ( 260.60 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: .9180g/cm3 Molecular Formula: C14H22O Molecular Weight: 206.33 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, strong oxidants. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 5510-99-6: SK8225000 LD50/LC50: CAS# 5510-99-6: Draize test, rabbit, eye: 50 ug/24H Severe; Draize test, rabbit, skin: 2 mg/24H Severe. Intravenous, rabbit: LDLo = 10 Carcinogenicity: Di-sec-butylphenol, tech. (predom. 2,6-isomer) - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: ALKYLPHENOLS, LIQUID, N.O.S. Hazard Class: 8 UN Number: 3145 Packing Group: III IMO Shipping Name: ALKYLPHENOLS, LIQUID, N.O.S. Hazard Class: 8 UN Number: 3145 Packing Group: III RID/ADR Shipping Name: ALKYLPHENOLS, LIQUID, N.O.S. Hazard Class: 8 UN Number: 3145 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 34 Causes burns. Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 5510-99-6: No information available. Canada CAS# 5510-99-6 is listed on Canada's NDSL List. CAS# 5510-99-6 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 5510-99-6 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
|
毒理学数据: 1、皮肤/眼睛刺激性 标准的Draize试验：兔子，皮肤接触：2mg/24H；反应的严重程度：严重。 标准的Draize试验：兔子，眼睛接触：50μg/24H；反应的严重程度：严重。 2 、急性毒性：小鼠经口LD50：60mg/kg；兔子经静脉LDLo：10mg/kg；
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
|
| 危害码 (欧洲) | Xi: Irritant; |
|---|---|
| 风险声明 (欧洲) | R36/37/38 |
| 安全声明 (欧洲) | S26;S27;S28;S45;S24/25;S36/S37/S39 |
| 危险品运输编码 | UN 3265 8/PG 2 |
| WGK德国 | 3 |
| RTECS号 | SK8225000 |
| 包装等级 | III |
| 海关编码 | 2907199090 |
| 海关编码 | 2907199090 |
|---|---|
| 中文概述 | 2907199090 其他一元酚. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2907199090 other monophenols VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0% |