| 中文名 | 双(2-乙氧基乙基)己二酸酯 |
|---|---|
| 英文名 | bis(2-ethoxyethyl) hexanedioate |
| 中文别名 | 双(2-乙氧乙基)己二酸酯 |
| 英文别名 |
bis-2-ethoxyethyl adipate
EINECS 203-673-0 Bis(2-ethoxyethyl) adipate Hexanedioic acid, bis(2-ethoxyethyl) ester MFCD00041926 |
| 密度 | 1.0±0.1 g/cm3 |
|---|---|
| 沸点 | 359.1±22.0 °C at 760 mmHg |
| 分子式 | C14H26O6 |
| 分子量 | 290.353 |
| 闪点 | 153.7±22.4 °C |
| 精确质量 | 290.172943 |
| PSA | 71.06000 |
| LogP | 1.57 |
| 蒸汽压 | 0.0±0.8 mmHg at 25°C |
| 折射率 | 1.442 |
| 储存条件 | 库房通风低温干燥 |
| 分子结构 | 五、分子性质数据： 1、 摩尔折射率：73.94 2、 摩尔体积（m3/mol）：279.3 3、 等张比容（90.2K）：677.9 4、 表面张力（dyne/cm）：34.7 5、 介电常数： 6、 偶极距（10 -24cm 3）： 7、 极化率：29.31 |
| 计算化学 | 1、 疏水参数计算参考值（XlogP）：1 2、 氢键供体数量：0 3、 氢键受体数量：6 4、 可旋转化学键数量：15 5、 互变异构体数量： 6、 拓扑分子极性表面积（TPSA）：71.1 7、 重原子数量：20 8、 表面电荷：0 9、 复杂度：228 10、同位素原子数量：0 11、确定原子立构中心数量：0 12、不确定原子立构中心数量：0 13、确定化学键立构中心数量：0 14、不确定化学键立构中心数量：0 15、共价键单元数量：1 |
| 更多 | 1. 性状：未确定 2. 密度（g/mL,25℃）：1.038 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC, 4mmHg）：164-166 7. 折射率（D20)：1.4410 8. 闪点（ºC）：未确定 9. 比旋光度（ºC）：未确定 10. 自燃点或引燃温度（ºC）: 未确定 11. 蒸气压（mmHg, 20ºC）：未确定 12. 饱和蒸气压（kPa, ℃)：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性：未确定 |
Synonym:Bis(2-ethoxyethyl)hexanedioate; Adipic acid, bis(2-ethoxyethyl) ester; Diethoxy ethyl adipate; Hexanedioic acid, bis(2-ethoxyethyl) ester; Hexanoic acid, bis(2-ethoxyethyl) este Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes. Potential Health Effects Eye: Causes eye irritation. May cause chemical conjunctivitis. Skin: May cause severe skin irritation. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Inhalation: Causes respiratory tract irritation. Can produce delayed pulmonary edema. Chronic: Effects may be delayed. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Use with adequate ventilation. Wash clothing before reuse. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 109-44-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Clear liquid Color: clear, colorless Odor: none reported pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 166 deg C @ 4.00mm Hg Freezing/Melting Point: Not available. Autoignition Temperature: Not applicable. Flash Point: 144 deg C ( 291.20 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Not available. Solubility in water: Not available. Specific Gravity/Density: Not available. Molecular Formula: C14H26O6 Molecular Weight: 290.35 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: Incompatible materials, excess heat, strong oxidants. Incompatibilities with Other Materials: No information found.. Hazardous Decomposition Products: Acrid smoke and fumes. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 109-44-4: AU9300000 LD50/LC50: CAS# 109-44-4: Draize test, rabbit, skin: 100 mg/24H Severe. Carcinogenicity: Bis(2-ethoxyethyl) adipate - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36 Irritating to eyes. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 39 Wear eye/face protection. WGK (Water Danger/Protection) CAS# 109-44-4: No information available. Canada CAS# 109-44-4 is listed on Canada's DSL List. CAS# 109-44-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 109-44-4 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
|
毒理学数据: 1、皮肤/眼睛刺激性 标准的Draize试验：人，皮肤接触：50mg/24H，反应的严重程度：轻度。 标准的Draize试验：大鼠，皮肤接触：100mg/24H，反应的严重程度：轻度。 标准的Draize试验：兔子，皮肤接触：100mg/24H，反应的严重程度：严重。 标准的Draize试验：豚鼠，皮肤接触：100mg/24H，反应的严重程度：轻度。
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
|
| 符号 |
GHS07 |
|---|---|
| 信号词 | Warning |
| 危害声明 | H315-H319-H335 |
| 警示性声明 | P261-P305 + P351 + P338 |
| 个人防护装备 | dust mask type N95 (US);Eyeshields;Gloves |
| 危害码 (欧洲) | Xi: Irritant; |
| 风险声明 (欧洲) | R36/37/38 |
| 安全声明 (欧洲) | S26-S36 |
| 危险品运输编码 | NONH for all modes of transport |
| WGK德国 | 3 |
| RTECS号 | AU9300000 |
| 海关编码 | 2918990090 |
| 海关编码 | 2918990090 |
|---|---|
| 中文概述 | 2918990090. 其他含其他附加含氧基羧酸（包括酸酐、酰卤化物、过氧化物和过氧酸及该税号的衍生物）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途 |
| Summary | 2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0% |
