10377-66-9

10377-66-9结构式

常用中文名：硝酸锰
常用英文名：Manganese(II) nitrate
CAS号：10377-66-9
分子式：MnN₂O₆
分子量：178.948
相关类别：无机化工无机盐金属硝酸盐及亚硝酸盐
发布时间：2018-08-22 16:47:15
更新时间：2024-01-02 17:53:10
用作微量分析测定银的试剂，也用于稀土元素的分离和陶瓷工业

中文名	硝酸锰
英文名	Manganese nitrate
中文别名	硝酸亚锰
英文别名	manganese dinitrate UNII-I389H78514 Manganese(II) nitrate Manganese(2+) dinitrate EINECS 233-828-8 MFCD00011112

密度	1.536 g/mL at 25 °C
沸点	100°C
熔点	37°C
分子式	MnN₂O₆
分子量	178.948
精确质量	178.913681
PSA	137.76000
LogP	0.56820
外观性状	透明灰白的-红色液体
储存条件	密封于阴凉干燥处。
稳定性	1.氧化剂。 2.加热时放出二氧化锰并放出氧化氮，有毒！吸入蒸气有毒！ 3.对眼睛、皮肤、黏膜和上呼吸道有刺激性。可引起呼吸道炎症和肺炎
水溶解性	soluble
分子结构	1、摩尔折射率：无可用 2、摩尔体积（cm³/mol）：无可用 3、等张比容（90.2K）：无可用 4、表面张力（dyne/cm）：无可用
计算化学	1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:6 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积126 7.重原子数量:9 8.表面电荷:0 9.复杂度:18.8 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:3
更多	1. 性状：淡红色或玫瑰色透明液体。 2. 密度（g/mL,25/4℃）： 1.536 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：37 5. 沸点（ºC,常压）：100 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：无可用 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）：无可用 19. 溶解性：溶于水和醇

Name:	Manganese(II) Nitrate Material Safety Data Sheet
Synonym:
CAS:	10377-66-9

Section 1 - Chemical Product MSDS Name:Manganese(II) Nitrate Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
10377-66-9	Manganese(II) Nitrate	100.0	233-828-8

Hazard Symbols: O
Risk Phrases: 8

Section 3 - HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
Contact with combustible material may cause fire.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
No information regarding eye irritation and other potential effects was found.
Skin:
No information regarding skin irritation and other potential effects was found.
Ingestion:
The toxicological properties of this substance have not been fully investigated.
Inhalation:
The toxicological properties of this substance have not been fully investigated.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Oxidizer. Greatly increases the burning rate of combustible materials. May accelerate burning if involved in a fire.
May explode from heat or contamination. Containers may explode when heated.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or chemical foam. Cool containers with flooding quantities of water until well after fire is out. For small fires, do NOT use dry chemicals, carbon dioxide, halon or foams. USE WATER ONLY. For large fires flood fire with water from a distance.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with clothing and other combustible materials. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 10377-66-9: United Kingdom, WEL - TWA: (listed as manganese, inorganic compounds): 0.5 mg/m3 TWA United Kingdom, WEL - STEL: (listed as manganese, inorganic compounds): 1.5 mg/m3 STEL United States OSHA: 5 mg/m3 Ceiling (as Mn) (listed under Mangan compounds, n.o.s.).
Belgium - TWA: (listed as manganese compounds, n.o.s.): 0.2 mg/m3 (as Mn) Japan: (listed as manganese compounds, n.o.s.): 0.3 mg/m3 OEL (ex organic compounds, as Mn) Malaysia: (listed as manganese, inorganic compounds): 0.2 mg/m3 T (as Mn) Netherlands: (listed as manganese compounds, n.o.s.): 3 mg/m3 STE (as Mn) Netherlands: (listed as manganese compounds, n.o.s.): 1 mg/m3 MAC Mn) Spain: (listed as manganese, inorganic compounds): 0.2 mg/m3 VLA- (as Mn) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: N2O6.Mn
Molecular Weight: 124.0098

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, combustible materials, organic materials, reducing agents, strong acids.
Incompatibilities with Other Materials:
Acids (mineral, non-oxidizing, e.g. hydrochloric acid, hydrofluoric acid, muriatic acid, phosphoric acid), acids (organic, e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), alcohols and glycols (e.g. butyl alcohol, ethanol, methanol, ethylene glycol), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, formaldehyde), amides (e.g. butyramide, diethyltoluamide, dimethyl formamide), amines (aliphatic and aromatic, e.g. dimethyl amine, propylamine, pyridine, triethylamine), azo, diazo, and hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), carbamates (e.g. carbanolate, carbofuran), cyanides (e.g. potassium cyanide, sodium cyanide), dithiocarbamates (e.g. ferbam, maneb, metham, thiram), esters (e.g. butyl acetate, ethyl acetate, propyl formate), ethers (e.g. dioxane, furfuran, tetrahydrofuran (THF)), hydrocarbons (aromatic, e.g. benzene, chrysene, cumene, toluene), halogenated organics (e.g. dibromoethane, hexachlorobenzene, methyl chloride, trichloroethylene), isocyanates (e.g. methyl isocyanate), ketones (e.g. acetone, acetophenone, MEK, MIBK), mercaptans and other organic sulfides (e.g. butyl mercaptan, carbon disulfide, methanethiol), metals (alkali and alkaline, e.g. cesium, potassium, sodium), metals as powders (e.g. hafnium, raney nickel), metals as non-powders (e.g. brass, bronze, iron), nitrides (e.g. potassium nitride, sodium nitride), nitriles (e.g. acetonitrile, methyl cyanide), nitro compounds (organic, e.g. nitrobenzene, nitroglycerine, picric acid, trinitrotoluene), hydrocarbons (aliphatic, unsaturated, e.g. cyclopentene, ethylene, heptene), hydrocarbons (aliphatic, saturated, e.g. butane, heptane, isooctane), peroxides and hydroperoxides (organic, e.g. acetyl peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone peroxide), phenols and cresols (e.g. carbolic acid, creosote, cresol, phenol, resorcinol), organophosphates, phosphothioates (e.g. methylparathion, parathion, phorate, thionazin), sulfides (i.
Hazardous Decomposition Products:
Oxides of nitrogen.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 10377-66-9: QU9780000 LD50/LC50:
Not available.
Carcinogenicity:
Manganese(II) Nitrate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: MANGANESE NITRATE
Hazard Class: 5.1
UN Number: 2724
Packing Group: III
IMO
Shipping Name: MANGANESE NITRATE
Hazard Class: 5.1
UN Number: 2724
Packing Group: III
RID/ADR
Shipping Name: MANGANESE NITRATE
Hazard Class: 5.1
UN Number: 2724
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O
Risk Phrases:
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 10377-66-9: No information available.
Canada
CAS# 10377-66-9 is listed on Canada's DSL List.
CAS# 10377-66-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10377-66-9 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
N/A

毒理学数据:

试验方法：
摄入剂量： 50 mmol / L的
测试对象：细菌-枯草芽孢杆菌
毒性类型：突变
毒性作用：详细的毒副作用没有报告以外的其他致死剂量值。

生态学数据:

该物质对环境可能有危害，对水体应给予特别注意。

CHEMICAL IDENTIFICATION

RTECS NUMBER :: QU9780000

CHEMICAL NAME :: Nitric acid, manganese(2+) salt

CAS REGISTRY NUMBER :: 10377-66-9

LAST UPDATED :: 199712

DATA ITEMS CITED :: 24

MOLECULAR FORMULA :: N2-O6.Mn

MOLECULAR WEIGHT :: 178.96

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: DNA repair

TEST SYSTEM :: Bacteria - Bacillus subtilis

DOSE/DURATION :: 50 mmol/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 31,185,1975 *** REVIEWS *** ACGIH TLV-TWA 0.2 mg(Mn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:CL 5 mg(Mn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,149,1971 OSHA PEL (Gen Indu):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(Mn)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(Mn)/m3 JAN 1993 OEL-DENMARK:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-FINLAND:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-HUNGARY:TWA 0.3 mg(Mn)/m3;STEL 0.6 mg(Mn)/m3 JAN 1993 OEL-JAPAN:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Mn)/m3 JAN 1993 OEL-POLAND:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-SWEDEN:TWA 1 mg(Mn)/m3;STEL 2.5 mg(Mn)/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 2.5 mg(Mn)/m3;STEL 5 mg(Mn)/m3 (total dust) JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Mn)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81886 No. of Facilities: 41 (estimated) No. of Industries: 3 No. of Occupations: 4 No. of Employees: 841 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81886 No. of Facilities: 612 (estimated) No. of Industries: 10 No. of Occupations: 17 No. of Employees: 7066 (estimated) No. of Female Employees: 1070 (estimated)

符号	GHS03, GHS06
信号词	Danger
危害声明	H272-H315-H319-H331
警示性声明	P220-P261-P305 + P351 + P338-P311
个人防护装备	Eyeshields;Gloves
危害码 (欧洲)	O: Oxidizing agent;C: Corrosive;
风险声明 (欧洲)	R36/37/38
安全声明 (欧洲)	S17-S26-S27-S36/37/39-S45-S36
危险品运输编码	UN 3264 8/PG 3
WGK德国	1
包装等级	III
危险类别	5.1

1.将粉碎的含锰76%的金属铁合金分次少量的加到密度为1.2的稀硝酸中，并不断搅拌，保持金属锰过量：

当一氧化氮不再逸出时，加热反应液，趁热过滤，取出1／5滤液，加入碳酸铵至溶液呈弱碱性，并析出氢氧化铁和碳酸锰混合沉淀，用水仔细洗涤混合沉淀物后，再加回到 4／5的滤液中，在90～95℃下加热30min，趁热过滤，除去氢氧化铁沉淀。滤液用试剂硝酸酸化后，加热至70℃，以赶净碳酸铵，即可制得成品。

2.软锰矿法　将原料矿经焙烧还原成一氧化锰，用硝酸浸取，经净化、浓缩结晶得硝酸锰。主要化学反应如下：

3.菱锰矿法　原料矿与硝酸反应生成硝酸锰，因原料中伴生 CaCO3、MgCO3、FeCO3，经强酸高温反应，当PH＞4以上可除去铁，酌量加入 MnSO4·H2O，可除部分钙，但镁离子在反应液中难以去除，会影响产品质量。其主要反应如下：

4.金属锰法　金属锰与硝酸作用，可生产高纯度硝酸锰。主要化学反应如下：

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