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13463-12-2生产厂家

13463-12-2价格

13463-12-2

13463-12-2结构式
13463-12-2结构式

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中文名 溴化亚铁(II)水合物
英文名 Iron(II) bromide hydrate
英文别名 Ironbromidehydrateorangextl
沸点 937 °C at 760 mmHg
熔点 27ºC
分子式 Br2FeH2O
分子量 233.66800
精确质量 231.78200
PSA 9.23000
外观性状 深黄色固体
储存条件 2-8°C, 密封, 干燥, 惰性气体
稳定性

溶于水、乙醇和乙醚,在潮湿空气中易氧化。

分子结构

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:231.782167 Da

8、标称质量:232 Da

9、平均质量:233.6683 Da

更多

1. 性状:浅绿色至蓝绿色正交棱柱体,对光敏感。

2. 密度(g/mL,25/4℃):未确定

3. 相对蒸汽密度(g/mL,空气=1):未确定

4. 熔点(ºC):27

5. 沸点(ºC,常压):未确定

6. 沸点(ºC,5.2kPa):未确定

7. 折射率:未确定

8. 闪点(ºC):未确定

9. 比旋光度(º):未确定

10. 自燃点或引燃温度(ºC):不适用的

11. 蒸气压(kPa,25ºC):未确定

12. 饱和蒸气压(kPa,60ºC):未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC):未确定

15. 临界压力(KPa):未确定

16. 油水(辛醇/水)分配系数的对数值:未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V):未确定

19. 溶解性:未确定


Section 1: Product Identification
Chemical Name:Iron (II) bromide hydrate
CAS Registry Number:13463-12-2
Formula:FeBr2.XH2O
EINECS Number:none
Chemical Family:metal halide
Synonym:Ferrous bromide hydrate

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound13463-12-2100%1mg/m3no data

Section 3: Hazards Identification
Irritating to skin, eyes and respiratory tract. May cause liver damage. Material forms an acidic solution with
Emergency Overview:
water.
Primary Routes of Exposure:Contact with skin and eyes. Inhalation of dust.
Eye Contact:Causes moderate to severe irritation of the eyes.
Skin Contact:Causes irritation, redness, and pain to skin.
Inhalation:Dust causes coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting.
Ingestion:Soluble iron salts may cause poisoning.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Prolonged ingestion may lead to damage to the liver and pancreas. Prolonged inhalation of dusts may cause
Chronic Health Affects:
pulmonary fibrosis.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:none required
Special Fire Fighting Procedures:No special fire fighting procedures required.
Hazardous Combustion andnone
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable
Spill and Leak Procedures:
inert material and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store solid in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear appropriate chemical resistant gloves and protective clothing.
Ventilation:If possible, handle the material in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:greenish-black xtl.
Molecular Weight:215.67
Melting Point:27°
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:very soluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:chlorine
Decomposition Products:none

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
危害码 (欧洲) C
风险声明 (欧洲) 20-36/37/38
安全声明 (欧洲) 26-36

1.在隔绝空气下将铁粉溶于氢溴酸中,经浓缩、冷却后即析出六水合物的结晶。

2.由过量铁与溴水在水中作用而得,或由铁溶于氢溴酸后在低于49℃温度下蒸发而得。