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| 中文名 | 氯化鉬 |
|---|---|
| 英文名 | molybdenum (vi) tetrachloride oxide |
| 中文别名 | 四氯氧化钼 |
| 英文别名 |
MOLYBDENUM(VI) OXYCHLORIDE
MOLYBDENUM OXYTETRACHLORIDE oxidomolybdenum tetrachloride molybdenium oxytetrachloride MFCD00014222 tetrachloride(oxo)molybdenum(VI) Molybdenum (VI) tetrachloride oxide,Cl molybdenyl(VI) chloride Molybdenumtetrachlorideoxidemingreenpowder Molybdenum(VI) tetrachloride oxide,min. molybdenium(VI) oxotetrachloride Molybdenum tetrachloride oxide molybdenum oxotetrachloride |
| 熔点 | 100-101ºC |
|---|---|
| 分子式 | Cl4MoO |
| 分子量 | 253.77100 |
| 精确质量 | 253.77600 |
| PSA | 17.07000 |
| LogP | 2.63920 |
| 储存条件 | 密闭于阴凉干燥环境中 |
| 稳定性 | 遵照规定使用和储存则不会分解。空气中的微量水分也可引起分解。加热时，约从80℃起开始升华，在蒸发的同时，其中的一部分将放出氯气而分解。四氯一氧化钼具有光敏性。 |
| 分子结构 | 1、摩尔折射率：无可用 2、 摩尔体积（cm3/mol）：无可用 3、 等张比容（90.2K）：无可用 4、 表面张力（dyne/cm）：无可用 5、 极化率：无可用 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:4 3.氢键受体数量:1 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积17.1 7.重原子数量:6 8.表面电荷:0 9.复杂度:7.5 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:5 |
| 更多 | 1. 性状：暗绿色的结晶。 2. 密度（g/mL,25/4℃）：无可用 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：97 5. 沸点（ºC,常压）：无可用 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：无可用 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）：无可用 19. 溶解性：无可用 |
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Section 1: Product Identification Chemical Name:Molybdenum (VI) tetrachlorideoxide, min. 97% CAS Registry Number:13814-75-0 Formula:MoOCl4 EINECS Number:none Chemical Family:metal oxyhalide Synonym:Molybdenum oxychloride, tetrachloromolybdenum oxide.
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound13814-75-0100%10mg/m3( as Mo)5mg/m3 (as Mo) Section 3: Hazards Identification Corrosive to skin and eyes. Material hydrolyzes in contact with moisture releasing toxic and corrosive fumes of Emergency Overview: hydrogen chloride and aqueous hydrochloric acid. Primary Routes of Exposure:Contact with skin and eyes. Inhalation of dust. Eye Contact:Corrosive to the eyes. Skin Contact:Causes burns to the skin. Inhalation:Forms hydrogen chloride in the presence of moisture. Inhalation leads to burning of the respiratory tract. Ingestion:If large amounts ingested, severe burns to the gastrointestinal tract may occur. Corrosive to skin, eyes and respiratory tract and causes eye, skin burns, dyspnea (breathing difficulty), and Acute Health Affects: pulmonary edema Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in Inhalation: breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide, dry powder or foam. If involved in a fire, fire fighters should be equipped with NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may release corrosive hydrogen chloride fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be neutralized with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Spill and Leak Procedures:Large spills in areas not adequately ventilated will require an evacuation of site. Emergency response teams will require self-contained breathing apparatus. SECTION 7: Handling and Storage Store in a tightly sealed container. Keep away from heat, moisture and direct sunlight. Handle and store under Handling and Storage: a dry inert atmosphere of nitrogen or argon. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may emit corrosive fumes. Handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may emit corrosive fumes. Handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:green powder Molecular Weight:253.78 Melting Point:100-101° Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:pungent odor Solubility in Water:soluble SECTION 10: Stability and Reactivity Stability:air sensitive, moisture sensitive (store cold) Hazardous Polymerization:No hazardous polymerization. Conditions to Avoid:contact with air and moisture Incompatibility:active metals, water, alcohols, reducing agents. Decomposition Products:molybdenum oxides, chlorine and hydrogen chloride SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Corrosive solids, N.O.S. Hazard Class (CFR):8 Additional Hazard Class (CFR):NA Packaging Group (CFR):II UN ID Number (CFR):UN# 1759 Shipping Name (IATA):Corrosive solid, N.O.S. Hazard Class (IATA):8 Additional Hazard Class (IATA):NA Packaging Group (IATA):II UN ID Number (IATA):UN# 1759 SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。
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| 符号 |
GHS05 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H314 |
| 警示性声明 | P280-P305 + P351 + P338-P310 |
| 个人防护装备 | Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges |
| 危害码 (欧洲) | Xi: Irritant; |
| 风险声明 (欧洲) | 36/37/38 |
| 安全声明 (欧洲) | 26-37/39 |
| 危险品运输编码 | UN 3260 8/PG 3 |