122193-68-4

• 常用中文名：3-(2-全氟己基乙氧基)-1,2-环氧丙烷
• 常用英文名：3-[2-(Perfluorohexyl)ethoxy]-1,2-epoxypropane
• CAS号：122193-68-4
• 分子式：C₁₁H₉F₁₃O₂
• 分子量：420.167
• 发布时间：2018-10-10 13:47:33
• 更新时间：2025-08-27 11:40:11

名称

• 中文名: 3-[(2-全氟己基)乙氧基]-1,2-环氧丙烷
• 英文名: 3-[2-(Perfluorohexyl)ethoxy]-1,2-epoxypropane
• 中文别名: 3-(2-全氟己基乙氧基)-1,2-环氧丙烷; 3-(3,3,4,4,5,5,6,6,7,7,8,8,8-十三氟辛氧基)-1,2-环氧丙烷; 3-[2-(五氟己烷基)乙氧基]-1,2-环乙氧基丙烷
• 英文别名: 1,2-Epoxy-3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyloxy)propane; Oxirane, 2-[[(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)oxy]methyl]-; 3-(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyloxy)-1,2-epoxypropane; 2-{[(3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl)oxy]methyl}oxirane; 2-oxiranylmethyl 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl ether; 2-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctoxymethyl)oxirane

物化性质

• 密度: 1.5±0.1 g/cm3
• 沸点: 218.8±40.0 °C at 760 mmHg
• 分子式: C₁₁H₉F₁₃O₂
• 分子量: 420.167
• 闪点: 92.9±23.2 °C
• 精确质量: 420.039490
• PSA: 21.76000
• LogP: 5.20
• 蒸汽压: 0.2±0.4 mmHg at 25°C
• 折射率: 1.331
• 储存条件: 室温
• 分子结构:

  1、摩尔折射率：56.25

  2、摩尔体积（cm³/mol）：274.8

  3、等张比容（90.2K）：581.1

  4、表面张力（dyne/cm）：19.9

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：22.3

  7、单一同位素质量：420.039496 Da

  8、标称质量：420 Da

  9、平均质量：420.1672 Da

• 计算化学:

  1.疏水参数计算参考值（XlogP）:4.6

  2.氢键供体数量:0

  3.氢键受体数量:15

  4.可旋转化学键数量:9

  5.互变异构体数量:无

  6.拓扑分子极性表面积21.8

  7.重原子数量:26

  8.表面电荷:0

  9.复杂度:499

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:1

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：未确定

  2. 密度（g/mL,20℃）：1.57

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC,KPa）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（Pa,20ºC）：未确定

  12. 饱和蒸气压（KPa,20ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定

MSDS

Section I.Chemical Product and Company Identification Chemical Name 3-[2-(Perfluorohexyl)ethoxy]-1,2-epoxypropane Portland OR Synonym Oxirane, [[(3,3,4,4,5,5,6,6,7,7,8,8,8- tridecafluorooctyl)oxy]methyl]- (9 CI) Chemical Formula C 11 H 9 F 13 O 2 CAS Number 122193-68-4 (International) Section II.Composition and Information on Ingredients Chemical NameCAS Number Percent (%)TLV/PELToxicology Data 3-[2-(Perfluorohexyl)ethoxy]-1,2-epoxypropane122193-68-4Min. 96.0 (GC)Not available.Not available. Section III.Hazards Identification Acute Health Effects N o specific inform ation is available in our data base regarding the toxic effects of this m aterial for hum ans. H ow ever, exposure to any chem ical should be kept to a m inim u m . Skin and eye contact m ay result in irritation. M ay be harm ful if inhaled or ingested. A lw ays follow safe industrial hygiene practices and w ear proper protective equipm ent w hen handling this compound. Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound. Chronic Health Effects CARCINOGENIC EFFECTS : Not available. MUTAGENIC EFFECTS : Not available. TERATOGENIC EFFECTS : Not available. DEVELOPMENTAL TOXICITY : Not available. Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions. Section IV.First Aid Measures Eye Contact C heck for and rem ove any contact lenses. In case of contact, im m ediately flush eyes w ith plenty of w ater for at least 15 minutes. Get medical attention. Skin Contact In case of contact, im m ediately flush skin w ith plenty of w ater. Rem ove contam inated clothing and shoes. W ash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. Inhalation If the victim is not breathing, perform m outh-to-m outh resuscitation. Loosen tight clothing such as a collar, tie, belt or w aistband. If breathing is difficult, oxygen can be adm inistered. Seek m edical attention if respiration problem s do not improve. Ingestion IN D U C E V O M ITIN G by sticking finger in throat. Low er the head so that the vom it w ill not reenter the m outh and throat. Loosen tight clothing such as a collar, tie, belt or w aistband. If the victim is not breathing, perform m outh-to-m outh resuscitation. Exam ine the lips and m outh to ascertain w hether the tissues are dam aged, a possible in dication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Section V.Fire and Explosion Data FlammabilityAuto-IgnitionNot available. May be combustible at high temperature. Flash PointsFlammable Limits Not available.Not available. Combustion Products These products are toxic carbon oxides (CO, CO2), halogenated compounds. WARNING: Highly toxic HF gas is produced during combustion. Fire Hazards Not available. Explosion Hazards Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Fire Fighting Media Combustible liquid. and InstructionsSMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet. Consult with local fire authorities before attempting large scale fire-fighting operations. Continued on Next Page 3-[2-(Perfluorohexyl)ethoxy]-1,2-epoxypropane Section VI.Accidental Release Measures Spill Cleanup Combustible material. InstructionsK eep aw ay from heat. M echanical exhaust required. Stop leak if w ithout risk. Finish cleaning the spill by rinsing any contam inated surfaces w ith copious am ounts of w ater. C onsult federal, state, and/or local authorities for assistance on disposal. Section VII.Handling and Storage Handling and Storage C O M BU STIBLE. K eep aw ay from heat. M echanical exhaust required.A void excessive heat and light.D o not breathe gas/fumes/ vapor/spray. Information Always store away from incompatible compounds such as oxidizing agents. Section VIII.Exposure Controls/Personal Protection Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash station and safety shower is proximal to the work-station location. Personal Protection Splash goggles. Lab coat. V apor respirator. Boots. G loves. Suggested protective clothing m ight not be sufficient; consult a specialist BEFORE handling this product. Be sure to use a MSHA/NIOSH approved respirator or equivalent. Exposure Limits Not available. Section IX.Physical and Chemical Properties Solubility Physical state @ 20°C Liquid. (Clear, colorless.)Not available. Specific Gravity1.57 (water=1) Molecular WeightPartition Coefficient 420.17Not available. Boiling Point Vapor Pressure Not available.Not available. Melting PointVapor Density Not available.Not available. Refractive IndexVolatility 1.338 - 1.341Not available. Critical TemperatureOdor Not available.Not available. ViscosityTaste Not available.Not available. Section X.Stability and Reactivity Data Stability This material is stable if stored under proper conditions. (See Section VII for instructions) Conditions of Instability Avoid excessive heat and light. Incompatibilities Reactive with oxidizing agents. Section XI.Toxicological Information RTECS Number Not available. Routes of ExposureEye Contact. Ingestion. Inhalation. Toxicity Data Not available. Chronic Toxic EffectsCARCINOGENIC EFFECTS : Not available. MUTAGENIC EFFECTS : Not available. TERATOGENIC EFFECTS : Not available. DEVELOPMENTAL TOXICITY : Not available. Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions. Acute Toxic Effects N o specific inform ation is available in our data base regarding the toxic effects of this m aterial for hum ans. H ow ever, exposure to any chem ical should be kept to a m inim u m . Skin and eye contact m ay result in irritation. M ay be harm ful if inhaled or ingested. A lw ays follow safe industrial hygiene practices and w ear proper protective equipm ent w hen handling this compound. Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound. Continued on Next Page 3-[2-(Perfluorohexyl)ethoxy]-1,2-epoxypropane Section XII.Ecological Information Ecotoxicity Not available. Environmental Fate Not available. Section XIII.Disposal Considerations Waste DisposalRecycle to process, if possible. C onsult your local regional authorities. You m ay be able to dissolve or m ix m aterial w ith a com bustible solvent and burn in a chem ical incinerator equipped w ith an afterburner and scrubber system . O bserve all federal, state and local regulations when disposing of the substance. Section XIV.Transport Information DOT Classification Not a DOT controlled material (United States). PIN Number Not applicable. Proper Shipping Name Not applicable. Packing Group (PG) Not applicable. DOT Pictograms Section XV.Other Regulatory Information and Pictograms TSCA Chemical Inventory T h is p r o d u c t is NOT o n t h e E P A T o x ic S u b s t a n c e s C o n t r o l A c t (T S C A ) in v e n t o r y . T h e f o llo w in g n o t ic e s a r e r e q u ir e d b y 4 0 (EPA)CFR 720.36 (C) for those products not on the inventory list: (i) These products are supplied solely for use in research and developm ent by or under the supervision of a technically qualified individual as defined in 40 CFR 720.0 et sec. (ii) The health risks of these products have not been fully determ ined. A ny inform ation that is or becom es available w ill be supplied on an MSDS sheet. WHMIS Classification CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). (Canada) EINECS Number (EEC) Not available. EEC Risk Statements Not available. Japanese Regulatory Data Not available. Section XVI. Version 1.0 Validated on 1/2/2007. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): F
• 海关编码: 2910900090

海关

海关编码	2910900090
中文概述	2910900090. 三节环环氧化物，环氧醇（酚，醚），包括其卤化，磺化，硝化或亚硝化的衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%