19559-06-9

• 常用中文名：氯化钒(III)四氢呋喃加合物
• 常用英文名：trichlorotris(tetrahydrofuran)vanadium
• CAS号：19559-06-9
• 分子式：C₄H₈Cl₃OV
• 分子量：229.40600
• 发布时间：2018-08-29 19:33:34
• 更新时间：2024-01-02 18:06:26
• 下载msds

名称

• 中文名: 三氯化矾四氢呋喃络合物
• 英文名: trichlorotris(tetrahydrofuran)vanadium
• 英文别名: Vanadium(III) chloride-tetrahydrofuran complex (1:3),0.5M solution in methylene chloride,AcroSeal; VANADIUM(III) CHLORIDE-TETRAHYDROFURAN C OMPLEX (1:3),0.5M SOLN IN CH2CL2; Vanadium(III) chloride-tetrahydrofuran complex; Vanadium(III) chloride-tetrahydrofuran complex (1:3) solution; MFCD00145515; VANADIUM (III) CHLORIDE TETRAHYDROFURAN ADDUCT; [VCl3(tetrahydrofuran)3]; Vanadiumchloridetetrahydrofuranadductredxtl; trichlorotris(tetrahydrofuran)vanadium(III); VANADIUM(III) CHLORIDE TETRAHYDROFURAN COMPLEX (1:3); [VCl3(thf)3]

物化性质

• 密度: 1.312 g/mL at 25ºC
• 沸点: 40ºC
• 熔点: 265ºC (dec.)(lit.)
• 分子式: C₄H₈Cl₃OV
• 分子量: 229.40600
• 闪点: 18 °F
• 精确质量: 227.90800
• PSA: 9.23000
• LogP: 2.86530
• 蒸汽压: 152mmHg at 25°C
• 计算化学:

  1、 氢键供体数量：4

  2、 氢键受体数量：7

  3、 可旋转化学键数量：1

  4、 互变异构体数量：9

  5、 拓扑分子极性表面积（TPSA）：141

  6、 重原子数量：13

  7、 表面电荷：0

  8、 复杂度：117

  9、 同位素原子数量：0

  10、 确定原子立构中心数量：0

  11、 不确定原子立构中心数量：0

  12、 确定化学键立构中心数量：0

  13、 不确定化学键立构中心数量：0

  14、 共价键单元数量：2

• 更多:

  1. 性状：不确定

  2. 密度（g/mL,25/4℃）：1.312

  3. 相对蒸汽密度（g/mL,空气=1）：不确定

  4. 熔点（ºC）：265°C (dec.)(lit.)

  5. 沸点（ºC,常压）：不确定

  6. 沸点（ºC, 5mm ）：40

  7. 折射率：不确定

  8. 闪点（ºF）：18

  9. 比旋光度（º）：不确定

  10. 自燃点或引燃温度（ºC）：不确定

  11. 蒸气压（kPa,25ºC）：不确定

  12. 饱和蒸气压（kPa,60ºC）：不确定

  13. 燃烧热（KJ/mol）：不确定

  14. 临界温度（ºC）：不确定

  15. 临界压力（KPa）：不确定

  16. 油水（辛醇/水）分配系数的对数值：不确定

  17. 爆炸上限（%,V/V）：不确定

  18. 爆炸下限（%,V/V）：不确定

  19. 溶解性：不确定

MSDS

Section 1: Product Identification Chemical Name:Vanadium (III) chloride tetrahydrofuran adduct CAS Registry Number:19559-06-9 Formula:VCl3(C4H8O)2-3 EINECS Number:none Chemical Family:metal halide Synonym:Vanadium trichloride tetrahydrofuran adduct Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound19559-06-9100%no datano data Section 3: Hazards Identification Corrosive to skin and eyes. May release toxic and corrosive fumes of hydrogen chloride and aqueous Emergency Overview: hydrochloric acid. Tetrahydrofuran can cause drowsiness and unconsciousness. Primary Routes of Exposure:Ingestion, inhalation, skin, eyes Eye Contact:Severe corrosive to the eyes. Exposure can lead to permanent eye damage. Skin Contact:Corrosive to skin. Contact can lead to redness, pain, blistering, ulceration, and scar formation. Inhalation of tetrahydrofuran vapor may cause coughing, nausea, dizziness, headache, drowsiness, and Inhalation: unconsciousness. Ingestion:Ingestion of tetrahydrofuran or hydrogen chloride may cause gastrointestinal and respiratory irritation. Inhalation of vapor induces drowsiness and may cause coughing, chest pains, difficulty in breathing, nausea, Acute Health Affects: dizziness, headache and unconsciousness. Hydrogen chloride can cause pulmonary edema. Chronic Health Affects:In animal studies tetrahydrofuran acted as a tumorigen (liver), mutagen and reproductive effector. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus. Hazardous Combustion andIf involved in a fire this material may emit toxic fumes of hydrogen chloride, carbon monoxide, carbon dioxide, Decomposion Products:and organic fumes. Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Avoid Spill and Leak Procedures: raising dust. SECTION 7: Handling and Storage Store solid in a tightly sealed container away from moisture. Handle in a fume hood under a dry atmosphere of Handling and Storage: air or nitrogen. Prolonged exposure to the atmosphere may degrade the product. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. Ventilation:The solid may form corrosive vapors. It should be handled in an efficient fume hood. If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators Respirator: requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:The solid may form corrosive vapors. It should be handled in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:red xtl. Molecular Weight:157.3 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:pungent odor Solubility in Water:reacts with water SECTION 10: Stability and Reactivity Stability:moisture sensitive (store cold) Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:contact with moisture Incompatibility:Water, alcohols, oxidizing agents, oxygen and active metals Decomposition Products:Vanadium oxychloride, hydrogen chloride, carbon dioxide, carbon monoxide, organic fumes. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Corrosive solids, N.O.S. Hazard Class (CFR):8 Additional Hazard Class (CFR):NA Packaging Group (CFR):II UN ID Number (CFR):UN# 1759 Shipping Name (IATA):Corrosive solid, N.O.S. Hazard Class (IATA):8 Additional Hazard Class (IATA):NA Packaging Group (IATA):II UN ID Number (IATA):UN# 1759 SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):See category code N770 for reporting. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 符号: GHS02, GHS05, GHS07
• 信号词: Danger
• 危害声明: H228-H302 + H312 + H332-H314
• 警示性声明: P210-P280-P305 + P351 + P338-P310
• 危害码 (欧洲): C: Corrosive;F: Flammable;
• 风险声明 (欧洲): 20/21/22-34-40-11
• 安全声明 (欧洲): 26-27-28-36/37/39-45-23-16
• 危险品运输编码: UN 2925 4.1/PG 2
• WGK德国: 3
• 包装等级: III
• 危险类别: 8

上下游产品

上游产品  0
下游产品  5
7440-62-2 363-72-4 25377-37-1 12185-35-2
12129-72-5