trichlorotris(tetrahydrofuran)vanadium

Synonym:Vanadium trichloride tetrahydrofuran adduct

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Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound19559-06-9100%no datano data

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Section 3: Hazards Identification
Corrosive to skin and eyes. May release toxic and corrosive fumes of hydrogen chloride and aqueous
Emergency Overview:
hydrochloric acid. Tetrahydrofuran can cause drowsiness and unconsciousness.
Primary Routes of Exposure:Ingestion, inhalation, skin, eyes
Eye Contact:Severe corrosive to the eyes. Exposure can lead to permanent eye damage.
Skin Contact:Corrosive to skin. Contact can lead to redness, pain, blistering, ulceration, and scar formation.
Inhalation of tetrahydrofuran vapor may cause coughing, nausea, dizziness, headache, drowsiness, and
Inhalation:
unconsciousness.
Ingestion:Ingestion of tetrahydrofuran or hydrogen chloride may cause gastrointestinal and respiratory irritation.
Inhalation of vapor induces drowsiness and may cause coughing, chest pains, difficulty in breathing, nausea,
Acute Health Affects:
dizziness, headache and unconsciousness. Hydrogen chloride can cause pulmonary edema.
Chronic Health Affects:In animal studies tetrahydrofuran acted as a tumorigen (liver), mutagen and reproductive effector.
NTP:No
IARC:No
OSHA:No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus.
Hazardous Combustion andIf involved in a fire this material may emit toxic fumes of hydrogen chloride, carbon monoxide, carbon dioxide,
Decomposion Products:and organic fumes.
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

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SECTION 6: Accidental Release Measures
Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Avoid
Spill and Leak Procedures:
raising dust.

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SECTION 7: Handling and Storage
Store solid in a tightly sealed container away from moisture. Handle in a fume hood under a dry atmosphere of
Handling and Storage:
air or nitrogen. Prolonged exposure to the atmosphere may degrade the product.

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SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:The solid may form corrosive vapors. It should be handled in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:The solid may form corrosive vapors. It should be handled in an efficient fume hood.
Additional Protection:No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form:red xtl.
Molecular Weight:157.3
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:pungent odor
Solubility in Water:reacts with water

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SECTION 10: Stability and Reactivity
Stability:moisture sensitive (store cold)
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:contact with moisture
Incompatibility:Water, alcohols, oxidizing agents, oxygen and active metals
Decomposition Products:Vanadium oxychloride, hydrogen chloride, carbon dioxide, carbon monoxide, organic fumes.

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SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

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SECTION 12: Ecological Information
Ecological Information:No information available

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SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

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SECTION 14: Transportation
Shipping Name (CFR):Corrosive solids, N.O.S.
Hazard Class (CFR):8
Additional Hazard Class (CFR):NA
Packaging Group (CFR):II
UN ID Number (CFR):UN# 1759
Shipping Name (IATA):Corrosive solid, N.O.S.
Hazard Class (IATA):8
Additional Hazard Class (IATA):NA
Packaging Group (IATA):II
UN ID Number (IATA):UN# 1759

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SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):See category code N770 for reporting.
Second Ingredient:none

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SECTION 16 - ADDITIONAL INFORMATION
N/A