181418-64-4

• 常用中文名：三(2,2,6,6-四甲基-3,5-庚二酮基)钛(III)
• 常用英文名：tris(2,2,6,6-tetramethyl-3,5-heptanedionato)titanium (iii)
• CAS号：181418-64-4
• 分子式：C₃₃H₅₇O₆Ti
• 分子量：597.66900
• 发布时间：2018-12-26 18:27:52
• 更新时间：2025-08-25 11:31:50

名称

• 中文名: 三(2,2,6,6-四甲基-3,5-庚二酮酸)钛(III)
• 英文名: tris(2,2,6,6-tetramethyl-3,5-heptanedionato)titanium (iii)
• 中文别名: 钇(Ⅲ)(三甘醇二甲醚添加物)
• 英文别名: MFCD00145466

物化性质

• 沸点: 75ºC 0,1mm
• 分子式: C₃₃H₅₇O₆Ti
• 分子量: 597.66900
• 精确质量: 597.36300
• PSA: 78.90000
• LogP: 9.03750
• 储存条件:

  保存方法：密闭，阴凉，干燥处

• 稳定性:

  避氧化物、酸、水分、空气

• 更多:

  1. 性状：紫色晶体

  2. 密度（g/mL25 ºC,）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC,常压）：未确定

  6. 沸点（ºC0.1mmHg）：75

  7. 折射率：未确定

  8. 闪点（ºF0.1mmHg）：75

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（kPa,25ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：不能溶解于水的

MSDS

Section 1: Product Identification Chemical Name:Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)titanium(III), min. 97% Ti(TMHD)3 CAS Registry Number:181418-64-4 Formula:Ti(C11H19O2)3 EINECS Number:none Chemical Family:metal beta-diketonate complexes Synonym:Dipivaloylmethane, titanium complex Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound181418-64-4100%no datano data Section 3: Hazards Identification No reports could be found indicating specific hazards are associated with this material. Toxicity is probably Emergency Overview: minimal. Primary Routes of Exposure:Ingestion Eye Contact:May cause slight to mild irritation of the eyes. Skin Contact:May cause slight to mild irritation of the skin. Inhalation:(If dust) May be irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information on the physiological effects of ingestion. Acute Health Affects:May be irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical Skin Exposure: assistance if irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Ingestion:Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Store under argon in a tightly sealed container in a dry place. If container is left open, air and moisture will Handling and Storage: degrade this material. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear appropriate chemical resistant gloves and protective clothing. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators Respirator: requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:purple xtl. Molecular Weight:597.7 Melting Point:no data Boiling Point:subl. 75°C /0.1mm Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air sensitive, moisture sensitive Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:exposure to air and moisture. Incompatibility:oxidizing agents Decomposition Products:Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 1、其它有害作用：通常对水是不危害的，若无政府许可，勿将材料排入周围环境。

安全

• 风险声明 (欧洲): R36/37/38
• 安全声明 (欧洲): 26-36/37/39