| 中文名 | 2-(氯汞)-4-硝基酚 |
|---|---|
| 英文名 | chloro-(2-hydroxy-5-nitrophenyl)mercury |
| 英文别名 |
2-Hydroxy-5-nitro-phenylquecksilber(1+),Chlorid
2-Chloromercuri-4-nitrophenol 2-hydroxy-5-nitro-phenylmercury (1+),chloride chloro(2-hydroxy-5-nitrophenyl)mercury |
| 熔点 | 205ºC |
|---|---|
| 分子式 | C6H4ClHgNO3 |
| 分子量 | 374.14400 |
| 精确质量 | 374.95900 |
| PSA | 66.05000 |
| LogP | 1.68520 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 26/27/28 33 50/53 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Very toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.The toxicological properties of this material have not been fully investigated.Highly toxic. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: Harmful if inhaled. May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Get medical aid immediately. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Remove contaminated clothing and shoes. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Poison room locked. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels. Exposure Limits CAS# 24579-90-6: United States OSHA: 0.1 mg/m3 Ceiling (listed under Mercury, ary and inorganic compounds). Belgium - TWA: (listed as mercury, aryl and inorganic compounds): mg/m3 VLE (as Hg) France - VME: (listed as mercury, aryl and inorganic compounds): mg/m3 VME (as Hg) Germany: (listed as mercury, aryl and inorganic compounds): 0.1 m VME (as Hg) Malaysia: (listed as mercury, aryl and inorganic compounds): 0.1 mg/m3 TWA (as Hg) Spain: (listed as mercury, aryl and inorganic compounds): 0.1 mg/ VLA-ED (as Hg) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 205 deg C Autoignition Temperature: 445 deg C ( 833.00 deg F) Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C6H4ClHgNO3 Molecular Weight: 374.14 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, dust generation, strong oxidants. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, nitrogen oxides, irritating and toxic fumes and gases, mercury/mercury oxides. Hazardous Polymerization: Will not occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 24579-90-6 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-Chloromercuri-4-nitrophenol - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Other No information available. Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: PHENYLMERCURIC COMPOUND, N.O.S. Hazard Class: 6.1 UN Number: 2026 Packing Group: III IMO Shipping Name: PHENYLMERCURIC COMPOUND, N.O.S. Hazard Class: 6.1 UN Number: 2026 Packing Group: III RID/ADR Shipping Name: PHENYLMERCURIC COMPOUND, N.O.S. Hazard Class: 6.1 UN Number: 2026 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: T+ N Risk Phrases: R 26/27/28 Very toxic by inhalation, in contact with skin and if swallowed. R 33 Danger of cumulative effects. R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety Phrases: S 13 Keep away from food, drink and animal feeding stuffs. S 28A After contact with skin, wash immediately with plenty of water. S 36 Wear suitable protective clothing. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 60 This material and its container must be disposed of as hazardous waste. S 61 Avoid release to the environment. Refer to special instructions/safety data sheets. WGK (Water Danger/Protection) CAS# 24579-90-6: No information available. Canada CAS# 24579-90-6 is listed on Canada's NDSL List. CAS# 24579-90-6 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 24579-90-6 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 风险声明 (欧洲) | R26/27/28;R33;R50/53 |
|---|---|
| 安全声明 (欧洲) | S13-S28-S36-S45-S60-S61 |
| 海关编码 | 2931900090 |
| 海关编码 | 2931900090 |
|---|---|
| 中文概述 | 2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0% |
| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |