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| 中文名 | 1-甲基环丙烷-1-甲酸乙酯 |
|---|---|
| 英文名 | ethyl 1-methylcyclopropane-1-carboxylate |
| 英文别名 |
ethyl 1-methyl-1-cyclopropanecarboxylate
1-methyl-cyclopropanecarboxylic acid ethyl ester Cyclopropanecarboxylic acid, 1-methyl-, ethyl ester EINECS 275-461-6 Ethyl 1-methylcyclopropanecarboxylate 1-methylcyclopropanoic acid ethyl ester 1-Methylcyclopropancarbonsaeure-ethylester 1-Methyl-cyclopropancarbonsaeure-aethylester ethyl1-methylcyclopropanecarboxylate |
| 密度 | 1.0±0.1 g/cm3 |
|---|---|
| 沸点 | 140.7±8.0 °C at 760 mmHg |
| 分子式 | C7H12O2 |
| 分子量 | 128.169 |
| 闪点 | 30.6±0.0 °C |
| 精确质量 | 128.083725 |
| PSA | 26.30000 |
| LogP | 1.62 |
| 蒸汽压 | 6.1±0.3 mmHg at 25°C |
| 折射率 | 1.454 |
| 储存条件 | 2-8°C |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 10 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Flammable.Flammable liquid. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Flammable liquid and vapor. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Remove all sources of ignition. Use a spark-proof tool. Section 7 - HANDLING and STORAGE Handling: Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels. Exposure Limits CAS# 71441-76-4: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 136 deg C @760mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: 30 deg C ( 86.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 0.918 Molecular Formula: C7H12O2 Molecular Weight: 128 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, ignition sources. Incompatibilities with Other Materials: Strong oxidizing agents, acids, bases. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 71441-76-4 unlisted. LD50/LC50: Not available. Carcinogenicity: Ethyl 1-methylcyclopropane-1-carboxylate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: FLAMMABLE LIQUID, N.O.S.* Hazard Class: 3 UN Number: 1993 Packing Group: III IMO Shipping Name: FLAMMABLE LIQUID, N.O.S. Hazard Class: 3 UN Number: 1993 Packing Group: III RID/ADR Shipping Name: FLAMMABLE LIQUID, N.O.S. Hazard Class: 3 UN Number: 1993 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: R 10 Flammable. Safety Phrases: S 16 Keep away from sources of ignition - No smoking. WGK (Water Danger/Protection) CAS# 71441-76-4: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 71441-76-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 71441-76-4 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | F: Flammable; |
|---|---|
| 风险声明 (欧洲) | R10 |
| 安全声明 (欧洲) | S16 |
| 危险品运输编码 | UN 1993 |
| 包装等级 | III |
| 危险类别 | 3.2 |
| 海关编码 | 2916209090 |
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71441-76-4 |
| 文献：Journal of the American Chemical Society, , vol. 81, p. 1660,1665 |
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71441-76-4 |
| 文献：Journal of the Chemical Society, Chemical Communications, , # 23 p. 1446 - 1447 |
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71441-76-4 |
| 文献：Journal of the American Chemical Society, , vol. 135, # 16 p. 6030 - 6032 |
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详细
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| 文献：Liebigs Annalen der Chemie, , # 7 p. 1485 - 1491 |
| 上游产品 4 | |
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| 下游产品 5 | |
| 海关编码 | 2916209090 |
|---|---|
| 中文概述 | 2916209090 其他（环烷、环烯、环萜烯）一元羧酸（包括酸酐、酰卤化物，过氧化物和过氧酸及该税号的衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装 |
| 监管条件 | A.入境货物通关单 B.出境货物通关单 |
| 检验检疫 | R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验 |
| Summary | 2916209090 other cyclanic, cyclenic or cyclotherpenic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0% |
