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| 中文名 | 4-氨基二苯醚 |
|---|---|
| 英文名 | 4-Phenoxyaniline |
| 中文别名 |
4-苯氧基苯胺
4-苯氧基苯胺 |
| 英文别名 |
4-phenoxy aniline
Benzenamine,4-phenoxy EINECS 205-367-2 4-Aminophenyl Phenyl Ether 4-Phenoxyaniline 4-Amino-1-phenoxybenzene p-Aminophenyl phenyl ether 4-phenoxyanilin p-Phenoxyaniline Aniline,p-phenoxy 4-Aminodiphenyl Ether 4-Phenoxybenzenamine 4-phenoxy-phenylamine Benzenamine, 4-phenoxy- MFCD00007862 |
| 密度 | 1.1±0.1 g/cm3 |
|---|---|
| 沸点 | 320.0±25.0 °C at 760 mmHg |
| 熔点 | 82-84 °C(lit.) |
| 分子式 | C12H11NO |
| 分子量 | 185.222 |
| 闪点 | 155.8±16.4 °C |
| 精确质量 | 185.084061 |
| PSA | 35.25000 |
| LogP | 2.36 |
| 外观性状 | 棕色至绿色-棕色结晶片或粉末 |
| 蒸汽压 | 0.0±0.7 mmHg at 25°C |
| 折射率 | 1.619 |
| 储存条件 | 室温 |
| 水溶解性 | < 1 g/L (20 ºC) |
| 分子结构 | 分子性质数据： 1、 摩尔折射率：56.93 2、 摩尔体积（m3/mol）：162.3 3、 等张比容（90.2K）：424.2 4、 表面张力（3.0 dyne/cm）：46.6 5、 极化率（0.5 10 -24cm 3）：22.56 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:1 3.氢键受体数量:2 4.可旋转化学键数量:2 5.互变异构体数量:无 6.拓扑分子极性表面积35.2 7.重原子数量:14 8.表面电荷:0 9.复杂度:158 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
Synonym:4-Aminophenyl phenyl ethe Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 22 40 43 50/53 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful if swallowed. Limited evidence of a carcinogenic effect. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May be harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Possible risk of irreversible effects. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Do not allow water to get into the container because of violent reaction. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 139-59-3: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Crystalline powder Color: brown - green Odor: weak odor pH: Not available. Vapor Pressure: 13.3 hPa @180 deg C Viscosity: Not available. Boiling Point: 140 deg C @3hPa Freezing/Melting Point: 82-86 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: 385 deg C Solubility in water: <1g/l in water (20C) Specific Gravity/Density: Molecular Formula: C12H11NO Molecular Weight: 185.22 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents, acid anhydrides, chlorides. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 139-59-3: BY7930000 LD50/LC50: CAS# 139-59-3: Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 500 mg/24H Mild. Carcinogenicity: 4-Phenoxyaniline - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Other No information available. Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.* Hazard Class: 6.1 UN Number: 2811 Packing Group: III IMO Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing Group: III RID/ADR Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN N Risk Phrases: R 22 Harmful if swallowed. R 40 Limited evidence of a carcinogenic effect. R 43 May cause sensitization by skin contact. R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety Phrases: S 24 Avoid contact with skin. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 61 Avoid release to the environment. Refer to special instructions/safety data sheets. WGK (Water Danger/Protection) CAS# 139-59-3: No information available. Canada CAS# 139-59-3 is listed on Canada's NDSL List. CAS# 139-59-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 139-59-3 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
|
毒理学数据: 皮肤/眼睛刺激数据 兔子皮肤接触：500mg/24H轻度反应。 兔子眼睛接触：100mg/24H中度反应 致突变数据： 细菌-鼠伤寒沙门氏菌：25ug/plate 啮齿动物-鼠肝DNA合成：10umol/L
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
MUTATION DATA
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| 符号 |
GHS07 |
|---|---|
| 信号词 | Warning |
| 危害声明 | H302-H315-H317-H319-H335 |
| 警示性声明 | P261-P280-P305 + P351 + P338 |
| 个人防护装备 | dust mask type N95 (US);Eyeshields;Faceshields;Gloves |
| 危害码 (欧洲) | Xn:Harmful; |
| 风险声明 (欧洲) | R22;R43;R50/53;R68 |
| 安全声明 (欧洲) | S26-S36/37/39-S61-S45-S24 |
| 危险品运输编码 | NONH for all modes of transport |
| WGK德国 | 3 |
| RTECS号 | BY7930000 |
| 包装等级 | I; II; III |
| 海关编码 | 2922299090 |
| 上游产品 9 | |
|---|---|
| 下游产品 10 | |
| 海关编码 | 2922299090 |
|---|---|
| 中文概述 | 2922299090. 其他氨基(萘酚、酚)及醚、酯〔包括它们的盐, 但含有一种以上含氧基的除外〕. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装 |
| Summary | 2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0% |
![5-氨基-[1,1'-联苯]-2-醇结构式](https://www.chemsrc.com/caspic/166/19434-42-5.png)
