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| 中文名 | [二叔丁基(氯化)膦]二氯化钯(II)二聚体 |
|---|---|
| 英文名 | [Di-tert-butyl(chloro)phosphine]palladium(II) Dichloride Dimer |
| 英文别名 |
ditert-butyl(chloro)phosphane,palladium(2+),tetrachloride
[Di-tert-butyl(chloro)phosphine]palladiuM(II) Dichloride DiMer DICHLORO(CHLORODI-T-BUTYLPHOSPHINE)PALLADIUM(II) DIMER Bis(2-methyl-2-propanyl)phosphinous chloride - dichloropalladium (1:1) Dichloro[di-tert-butyl(chloro)phosphine]palladium(II) Dimer |
| 沸点 | 191.6ºC at 760 mmHg |
|---|---|
| 熔点 | 222ºC (dec.) |
| 分子式 | C16H36Cl6P2Pd2 |
| 分子量 | 715.963 |
| 闪点 | 61.1ºC |
| 精确质量 | 711.849304 |
| PSA | 27.18000 |
| LogP | 11.19620 |
| 外观性状 | 固体;Light yellow to Amber to Dark green powder to crystal |
| 储存条件 | 室温，干燥 |
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[Di-tert-butyl(chloro)phosphine]palladium(II) Dichloride Revision number: 5
Dimer SAFETY DATA SHEET Section1. IDENTIFICATION Product name:[Di-tert-butyl(chloro)phosphine]palladium(II) Dichloride Dimer Section2. HAZARDS IDENTIFICATION
GHS classification
PHYSICAL HAZARDS Category 1 Corrosive to metals HEALTH HAZARDS Category 1C Skin corrosion/irritation Serious eye damage/eye irritationCategory 1 ENVIRONMENTAL HAZARDSNot classified GHS label elements, including precautionary statements Pictograms or hazard symbols Signal wordDanger May be corrosive to metals Hazard statements Causes severe skin burns and eye damage Precautionary statements: [Prevention]Keep only in original container. Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands thoroughly after handling. Wear protective gloves/eye protection/face protection. [Response]IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or doctor/physician. Absorb spillage to prevent material damage. [Storage]Store locked up. [Disposal]Dispose of contents/container through a waste management company authorized by the local government. [Di-tert-butyl(chloro)phosphine]palladium(II) Dichloride Dimer Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture:Substance Components:[Di-tert-butyl(chloro)phosphine]palladium(II) Dichloride Dimer Percent:>97.0%(T) CAS Number:386706-33-8 Synonyms:Dichloro[di-tert-butyl(chloro)phosphine]palladium(II) Dimer Chemical Formula:C16H36Cl6P2Pd2 Section4. FIRST AID MEASURES Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of soap and water. Immediately call a POISON CENTER or doctor/physician. Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/physician. Ingestion:Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. A rescuer should wear personal protective equipment, such as rubber gloves and air- Protection of first-aiders: tight goggles. Section5. FIRE-FIGHTING MEASURES Suitable extinguishingDry chemical, carbon dioxide. media: Unsuitable extinguishing Water media: Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to from the chemical:generate poisonous fume. Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Personal precautions,Use extra personal protective equipment (P3 filter respirator for toxic particles). Keep protective equipment and people away from and upwind of spill/leak. Entry to non-involved personnel should emergency procedures: be controlled around the leakage area by roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it. containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with up: appropriate laws and regulations. Prevention of secondary Do not allow contact with water. Remove all sources of ignition. Fire-extinguishing hazards:devices should be prepared in case of a fire. Use spark-proof tools and explosion- proof equipment. Section7. HANDLING AND STORAGE Precautions for safe handling Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment. Prevent dispersion of dust. Wash hands and face thoroughly after handling. Use a closed system if possible. Use a local exhaust if dust or aerosol will be generated. Advice on safe handling:Avoid contact with skin, eyes and clothing. May develop pressure. Open carefully. Use corrosive resistant equipment. [Di-tert-butyl(chloro)phosphine]palladium(II) Dichloride Dimer Section7. HANDLING AND STORAGE Conditions for safe storage, including any incompatibilities Storage conditions:Keep container tightly closed. Store in a cool and dark place. Store locked up. Store away from incompatible materials such as oxidizing agents. Packaging material:Comply with laws. Keep only in original container. Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Install a closed system or local exhaust. Also install safety shower and eye bath. Engineering controls: Personal protective equipment Respiratory protection: Dust respirator, self-contained breathing apparatus(SCBA), supplied air respirator, etc. Use respirators approved under appropriate government standards and follow local and national regulations. Hand protection:Impervious gloves. Safety goggles. A face-shield, if the situation requires. Eye protection: Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Solid Physical state (20°C): Form:Crystal- Powder Colour:Yellow - Deep yellow red No data available Odour: pH: No data available Melting point/freezing point:222°C (dec.) Boiling point/range:No data available No data available Flash point: Flammability or explosive limits: Lower:No data available No data available Upper: Relative density:No data available Solubility(ies): [Water]No data available No data available [Other solvents] Section10. STABILITY AND REACTIVITY Chemical stability:Stable under proper conditions. Possibility of hazardous Decomposes in contact with water and liberates toxic gases. reactions: Conditions to avoid:Moisture Incompatible materials: Oxidizing agents, Bases, Water Hazardous decomposition Carbon monoxide, Carbon dioxide, Phosphorus oxides, Hydrogen chloride products: Section11. TOXICOLOGICAL INFORMATION Acute Toxicity:No data available Skin corrosion/irritation: No data available Serious eyeNo data available damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: IARC =No data available No data available NTP = Reproductive toxicity:No data available [Di-tert-butyl(chloro)phosphine]palladium(II) Dichloride Dimer Section12. ECOLOGICAL INFORMATION Ecotoxicity: Fish:No data available Crustacea:No data available Algae:No data available Persistence / degradability: No data available BioaccumulativeNo data available potential(BCF): Mobility in soil Log Pow:No data available Soil adsorption (Koc):No data available Henry's LawNo data available constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION Hazards Class:8: Corrosive. UN-No:3265 Proper shipping name:Corrosive liquid, acidic, organic, n.o.s. Packing group:III Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | C |
|---|---|
| 危险品运输编码 | 3261.0 |
| 危险类别 | 8.0 |