3765-65-9

• 常用中文名：四戊基锡烷
• 常用英文名：Tetraamyltin
• CAS号：3765-65-9
• 分子式：C₂₀H₄₄Sn
• 分子量：403.273
• 发布时间：2018-09-08 08:40:08
• 更新时间：2025-08-25 14:24:13

名称

• 中文名: 四戊基锡烷
• 英文名: tetrapentylstannane
• 英文别名: Tin,tetrapentyl; Tetra-n-pentylzinn; Tetrapentylzinn; Tetrapentylstannane; Tetra-n-pentylstannan; Stannane,tetrapentyl; Stannane, tetrapentyl-; Tetraamyltin; Tetrapentyl-stannan; Tetraamylstannane; tetra-n-amyltin; Tetrapentyltin

物化性质

• 沸点: 393.7±25.0 °C at 760 mmHg
• 熔点: <0ºC
• 分子式: C₂₀H₄₄Sn
• 分子量: 403.273
• 闪点: 195.8±10.3 °C
• 精确质量: 404.246490
• LogP: 11.99
• 蒸汽压: 0.0±0.9 mmHg at 25°C
• 折射率: 1.4738

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : WH8636000 CHEMICAL NAME : Stannane, tetrapentyl- CAS REGISTRY NUMBER : 3765-65-9 BEILSTEIN REFERENCE NO. : 3904060 LAST UPDATED : 199712 DATA ITEMS CITED : 27 MOLECULAR FORMULA : C20-H44-Sn MOLECULAR WEIGHT : 403.33 WISWESSER LINE NOTATION : 5-SN-5&5&5 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 807 mg/kg TOXIC EFFECTS : Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Behavioral - muscle weakness REFERENCE : APFRAD Annales Pharmaceutiques Francaises. (SPPIF, B.P.22, F-41353 Vineuil, France) V.1- 1943- Volume(issue)/page/year: 14,88,1956 TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 202 mg/kg TOXIC EFFECTS : Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Behavioral - muscle weakness REFERENCE : APFRAD Annales Pharmaceutiques Francaises. (SPPIF, B.P.22, F-41353 Vineuil, France) V.1- 1943- Volume(issue)/page/year: 14,88,1956 TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 121 mg/kg TOXIC EFFECTS : Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Behavioral - muscle weakness REFERENCE : APFRAD Annales Pharmaceutiques Francaises. (SPPIF, B.P.22, F-41353 Vineuil, France) V.1- 1943- Volume(issue)/page/year: 14,88,1956 TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Intramuscular SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1613 mg/kg TOXIC EFFECTS : Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Behavioral - muscle weakness REFERENCE : APFRAD Annales Pharmaceutiques Francaises. (SPPIF, B.P.22, F-41353 Vineuil, France) V.1- 1943- Volume(issue)/page/year: 14,88,1956 TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Parenteral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 403 mg/kg TOXIC EFFECTS : Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) REFERENCE : COREAF Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. (Paris, France) V.1-261, 1835-1965. For publisher information, see CRASEV. Volume(issue)/page/year: 239,1091,1954 *** REVIEWS *** ACGIH TLV-TWA 0.1 mg(Sn)/m3;STEL 0.2 mg/m3 (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.1 mg(Sn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,258,1971 OSHA PEL (Gen Indu):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-BELGIUM:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-DENMARK:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-FINLAND:TWA 0.1 mg(Sn)/m3;STEL 0.3 mg(Sn)/m3;Skin JAN 1993 OEL-FRANCE:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3 JAN 1993 OEL-GERMANY:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-HUNGARY:STEL 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-THE PHILIPPINES:TWA 0.1 mg(Sn)/m3 JAN 1993 OEL-SWEDEN:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL-THAILAND:TWA 0.1 mg(Sn)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

安全

• 风险声明 (欧洲): 20/21/22-36/37/38
• 危险品运输编码: UN 2788
• 包装等级: III
• 危险类别: 6.1(b)
• 海关编码: 2931900090

合成路线

25637-27-8 ~0% 21227-23-6 3765-65-9

文献：Jousseaume, Bernard; Chanson, Evelyne; Pereyre, Michel Organometallics, 1986 , vol. 5, p. 1271 - 1272

693-25-4 7789-67-5 ~90% 3765-65-9

文献：Foeldesi, I. Acta Chimica Academiae Scientiarum Hungaricae, 1965 , vol. 45, p. 237 - 244 Full Text Show Details Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.8, page 113 - 114

543-59-9 ~% 3765-65-9

文献：Zietz, J. R.; Blitzer, S. M.; Redman, H. E.; Robinson, G. C. Journal of Organic Chemistry, 1957 , vol. 22, p. 60 - 62

628-17-1 ~% 3765-65-9

文献：Grimm, A. Journal fuer Praktische Chemie (Leipzig), 1854 , vol. 62, p. 385 - 414 Full Text Show Details Grimm, A. Liebigs Annalen der Chemie, 1854 , vol. 92, p. 384 - 394

693-25-4 ~% 3765-65-9

文献：Caujolle et al. Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1954 , vol. 239, p. 1091

693-25-4 7646-78-8 ~% 3765-65-9

文献：Jones, W. J.; Evans, D. P.; Gubwell, T.; Griffiths, D. C. Journal of the Chemical Society, 1935 , p. 39 - 47 Full Text View citing articles Show Details Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.8, page 113 - 114

海关

海关编码	2931900090
中文概述	2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
Summary	2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%