Organometallics

Reduction of bis (triorganotin) oxides by metals: an easy route to hexaorganoditins

B Jousseaume, E Chanson, M Pereyre

文献索引：Jousseaume, Bernard; Chanson, Evelyne; Pereyre, Michel Organometallics, 1986 , vol. 5, p. 1271 - 1272

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被引用次数: 12

摘要

2.115 and 2.144 A. The two sets of trans Os-C bonds are of approximately equal angles (144.2O and 144.8O). The N-Os distance in 1, 1.631 A is longer than that of the tetrachloro complex, 1.604 A, and even longer than that of [Os(N)C&]K2, 1.614 klS This is consistent with changes in the IR spectrum. The nitrogen-osmium stretching vibration is at lower energy in the alkyl complex than in [Os(N)Cl,]-, decreasing to 1100 from 1123 cm-l. In Os(NMe)(CH+ ...