The Journal of Organic Chemistry

REACTION OF TRIPHENYLTIN-LITHIUM WITH ORGANIC HALIDES

H GILMAN, SD ROSENBERG

文献索引：Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.16.1.1, page 141 - 147 Full Text Show Details Gilman, H.; Rosenberg, S. D. Journal of Organic Chemistry, 1953 , vol. 18, p. 680 - 685

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被引用次数: 2

摘要

The preparation of triphenyltin-lithium from stannous chloride and phenyllithium has been described (l), and this article reports the findings of more extensive investigation into the chemical nature of the organometallic complex. Triphenyltin-lithium is thought to be a complex formed by the addition of phenyllithium to diphenyltin (2). The central tin atom in diphenyltin has an open octet which is readily filled by the phenyl anion of phenyllithium.** ...