查看所有供应商和价格请点击：
| 中文名 | 二氯[(S)-(-)-2,2''-双(二苯基膦基)-1,1''-联萘基] [(2S)-(+)-1,1-双(4-甲氧基苯基)-3-甲基-1,2-丁二胺]钌(II)二氯甲烷加合物 |
|---|---|
| 英文名 | (2S)-1,1-bis(4-methoxyphenyl)-3-methyl-butane-1,2-diamine, dichlo roruthenium, [1-(2-diphenylphosphanyl-1-naphthyl)-2-naphthyl]-dip henyl-phosphane |
| 英文别名 |
RuCI2[(R)-BINAP][(R)-DAIPEN]
Dichloro[(R)-(+)-2,2 inverted exclamation marka-bis(diphenylphosphino)-1,1 inverted exclamation marka-binaphthyl][(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCI2[(S)-BINAP][(S)-DAIPEN] |
| 分子式 | C63H58Cl2N2O2P2Ru |
|---|---|
| 分子量 | 1109.07000 |
| 精确质量 | 1108.24000 |
| PSA | 97.68000 |
| LogP | 7.47440 |
| 储存条件 | 密闭于0-6 ºC阴凉干燥环境中 |
| 稳定性 | 遵照规定使用和储存则不会分解。 |
| 分子结构 | 1、摩尔折射率：无可用 2、 摩尔体积（cm3/mol）：无可用 3、 等张比容（90.2K）：无可用 4、 表面张力（dyne/cm）：无可用 5、 极化率：无可用 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:3 3.氢键受体数量:3 4.可旋转化学键数量:7 5.互变异构体数量:2 6.拓扑分子极性表面积50.4 7.重原子数量:24 8.表面电荷:0 9.复杂度:353 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:2 |
| 更多 | 1. 性状：无可用 2. 密度（g/mL,25/4℃）：无可用 3. 相对蒸汽密度（g/mL,空气=1）：无可用 4. 熔点（ºC）：无可用 5. 沸点（ºC,常压）：无可用 6. 沸点（ºC,5.2kPa）：无可用 7. 折射率：无可用 8. 闪点（ºC）：无可用 9. 比旋光度（º）：无可用 10. 自燃点或引燃温度（ºC）：无可用 11. 蒸气压（kPa,25ºC）：无可用 12. 饱和蒸气压（kPa,60ºC）：无可用 13. 燃烧热（KJ/mol）：无可用 14. 临界温度（ºC）：无可用 15. 临界压力（KPa）：无可用 16. 油水（辛醇/水）分配系数的对数值：无可用 17. 爆炸上限（%,V/V）：无可用 18. 爆炸下限（%,V/V）：无可用 19. 溶解性：无可用 |
|
Section 1: Product Identification Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-b Chemical Name: utanediamine]ruthenium (II) dichloromethane adduct, min CAS Registry Number:212143-24-3 Formula:C63H58Cl2N2O2P2Ru EINECS Number:none
Chemical Family:organometallic complex Synonym:Ruthenium [(S)-BINAP] [(S)-DAIPEN] Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound212143-24-3100%no datano data Section 3: Hazards Identification Emergency Overview:No particular hazard associated with this material. Primary Routes of Exposure:Ingestion Eye Contact:May cause irritation to the eyes Skin Contact:May cause slight to mild irritation of the skin. Inhalation:Inhalation is an unlikely source of exposure. Ingestion:No information is available on the physiological effects of ingestion. Other than a possible irritant, no information is available on the acute health effects of exposure to this Acute Health Affects: material. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:none Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam If this material is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage The material will degrade on prolonged exposure to air. Store under an inert atmosphere of nitrogen or argon. Handling and Storage:Keep bottle tightly sealed and away from heat and direct sunlight. For prolonged storage keep material refrigerated. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white to pale yellow powder Molecular Weight:1109.10 Melting Point:>100° (dec) Boiling Point:decomposes Vapor Pressure:not applicable Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air-sensitive solid (store cold) Hazardous Polymerization:none Conditions to Avoid:none Incompatibility:strong oxidizing agents carbon dioxide, carbon monoxide, hydrogen chloride, phosphorus pentoxide, nitrogen oxides, organic fumes, Decomposition Products: and ruthenium salts SECTION 11: Toxicological Information RTECS Data:No data available in the RTECS files Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:not listed on the TSCA inventory SARA (Title 313):not regulated by Title 313 Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
|
生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。
|
| 安全声明 (欧洲) | S22-S24/25 |
|---|