212143-24-3

212143-24-3 structure
212143-24-3 structure

Name (2S)-1,1-bis(4-methoxyphenyl)-3-methyl-butane-1,2-diamine, dichlo roruthenium, [1-(2-diphenylphosphanyl-1-naphthyl)-2-naphthyl]-dip henyl-phosphane
Synonyms RuCI2[(R)-BINAP][(R)-DAIPEN]
Dichloro[(R)-(+)-2,2 inverted exclamation marka-bis(diphenylphosphino)-1,1 inverted exclamation marka-binaphthyl][(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
RuCI2[(S)-BINAP][(S)-DAIPEN]
Molecular Formula C63H58Cl2N2O2P2Ru
Molecular Weight 1109.07000
Exact Mass 1108.24000
PSA 97.68000
LogP 7.47440

Section 1: Product Identification
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-b
Chemical Name:
utanediamine]ruthenium (II) dichloromethane adduct, min
CAS Registry Number:212143-24-3
Formula:C63H58Cl2N2O2P2Ru
EINECS Number:none
Chemical Family:organometallic complex
Synonym:Ruthenium [(S)-BINAP] [(S)-DAIPEN]

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound212143-24-3100%no datano data

Section 3: Hazards Identification
Emergency Overview:No particular hazard associated with this material.
Primary Routes of Exposure:Ingestion
Eye Contact:May cause irritation to the eyes
Skin Contact:May cause slight to mild irritation of the skin.
Inhalation:Inhalation is an unlikely source of exposure.
Ingestion:No information is available on the physiological effects of ingestion.
Other than a possible irritant, no information is available on the acute health effects of exposure to this
Acute Health Affects:
material.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:none
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
If this material is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
The material will degrade on prolonged exposure to air. Store under an inert atmosphere of nitrogen or argon.
Handling and Storage:Keep bottle tightly sealed and away from heat and direct sunlight. For prolonged storage keep material
refrigerated.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white to pale yellow powder
Molecular Weight:1109.10
Melting Point:>100° (dec)
Boiling Point:decomposes
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air-sensitive solid (store cold)
Hazardous Polymerization:none
Conditions to Avoid:none
Incompatibility:strong oxidizing agents
carbon dioxide, carbon monoxide, hydrogen chloride, phosphorus pentoxide, nitrogen oxides, organic fumes,
Decomposition Products:
and ruthenium salts

SECTION 11: Toxicological Information
RTECS Data:No data available in the RTECS files
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:not listed on the TSCA inventory
SARA (Title 313):not regulated by Title 313
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Safety Phrases S22-S24/25