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| 中文名 | 碘化钛(IV) |
|---|---|
| 英文名 | titanium (iv) iodide |
| 中文别名 |
碘化钛(Ⅳ)
四碘化钛 |
| 英文别名 |
iodine titanium
Titanium(4+) tetraiodide MFCD00043077 Titanium (IV) iodide Titanium(IV) iodide EINECS 231-754-0 titanium iodide TITANIUM TETRAIODIDE iodide titanium |
| 密度 | 4.3 g/cm3 |
|---|---|
| 沸点 | 377,1ºC |
| 熔点 | 150-151ºC |
| 分子式 | I4Ti |
| 分子量 | 555.485 |
| 精确质量 | 555.565796 |
| LogP | 3.54280 |
| 外观性状 | 红色-棕色晶体 |
| 储存条件 | 干性的保护气体下处置， 保持贮藏器密封 放入紧密的贮藏器内，储存在阴凉，干燥的地方 |
| 稳定性 | 如果遵照规格使用和储存则不会分解 避免接触水分/潮湿.在100～125℃有晶型转变点，高温型为立方晶系晶体，低温型晶体的对称性降低。吸湿性极强。溶于水并水解、发烟。难溶于石油醚。易溶于苯，更易溶于二硫化碳。 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:无 2.氢键供体数量:0 3.氢键受体数量:0 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积0 7.重原子数量:5 8.表面电荷:0 9.复杂度:19.1 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1. 性状：具有光泽的暗红褐色结晶。 2. 密度（g/mL 25ºC）：4.40 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：150 5. 沸点（ºC，常压）：377.2 6. 沸点（ºC,5.2kPa）：未确定 7. 折射率（n20/D）：未确定 8. 闪点（ºC，）：未确定 9. 比旋光度（º）：未确定 10. 自燃点或引燃温度（ºC）：未确定 11. 蒸气压（kPa,25ºC）：未确定 12. 饱和蒸气压（kPa,60ºC）：未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）：未确定 15. 临界压力（KPa）：未确定 16. 油水（辛醇/水）分配系数的对数值（25℃）：未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）：未确定 19. 溶解性(mg/mL)：溶于水，易水解 |
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Section 1: Product Identification Chemical Name:Titanium (IV) iodide (99.99%-Ti) PURATREM CAS Registry Number:7720-83-4 Formula:TiI4 EINECS Number:231-754-0 Chemical Family:metal halide Synonym:Titanium tetraiodide
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound7720-83-4100%no datano data Section 3: Hazards Identification Corrosive to skin, eyes, and mucous membranes. May cause coughing, wheezing, shortness of breath, Emergency Overview: headache, nausea and vomiting. Ingestion may cause damage to the mouth, throat and esophagus. Primary Routes of Exposure:Ingestion, inhalation, skin, eyes. Eye Contact:Corrosive to eyes. Skin Contact:Corrosive to skin. Inhalation:Inhalation may cause inflammation of the respiratory tract, edema and chemical pneumonitis. Ingestion:Ingestion may cause damage to the mouth, throat and esophagus. Corrosive to skin, eyes and mucous membranes. Inhalation causes coughing, wheezing, shortness of breath, Acute Health Affects: headache, nausea, and vomiting. Ingestion may cause damage to the mouth throat and esophagus. Chronic ingestion of iodides may produce iodism. Symptoms include skin rash, running nose, headache and Chronic Health Affects: irritation of mucous membranes. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:none required If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit corrosive hydrogen iodide fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Spill and Leak Procedures:Spillage in areas not adequately ventilated may require an evacuation of area. Emergency response teams will require self-contained breathing apparatus. SECTION 7: Handling and Storage Store material in a tightly sealed bottle away from moisture. If possible, handle material in an efficient fume Handling and Storage: hood. Prolonged exposure to the atmosphere may lead to degradation of the product. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. Ventilation:If possible, handle the material in an efficient fume hood. In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a Respirator: Respirator Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:black xtl. Molecular Weight:555.52 Melting Point:150° Boiling Point:377.1°C Vapor Pressure:no data Specific Gravity:4.3 Odor:Pungent odor. Solubility in Water:reacts with water SECTION 10: Stability and Reactivity Stability:moisture sensitive Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:contact with moisture Incompatibility:Oxidizing agents, water, alcohols, active metals and halogens Decomposition Products:with moisture: hydrogen iodide SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Corrosive Solid, Acidic, Inorganic, N.O.S. Hazard Class (CFR):8 Additional Hazard Class (CFR):NA Packaging Group (CFR):II UN ID Number (CFR):UN# 3260 Shipping Name (IATA):Corrosive Solid, Acidic, Inorganic, N.O.S. Hazard Class (IATA):8 Additional Hazard Class (IATA):NA Packaging Group (IATA):II UN ID Number (IATA):UN# 3260 SECTION 15: Regulatory Information TSCA:Listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
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生态学数据: 对水是稍微危害的，若无政府许可，勿将材料排入周围环境
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| 符号 |
GHS05 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H314 |
| 警示性声明 | P280-P305 + P351 + P338-P310 |
| 个人防护装备 | Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges |
| 危害码 (欧洲) | C |
| 风险声明 (欧洲) | R34 |
| 安全声明 (欧洲) | 26-36/37/39-45 |
| 危险品运输编码 | UN3260 |
| 包装等级 | II |
|
~%
7720-83-4 |
| 文献：Ann. Chim. Phys., , vol. 9, p. 229 - 237 Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 120, p. 290 - 296 Ti: MVol., 3.5, page 189 - 199 |
|
~%
7720-83-4 |
| 文献：Bulletin de la Societe Chimique de France, , p. 201 - 203 Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften, , p. 207 |
|
~%
7720-83-4 |
| 文献：Bulletin de la Societe Chimique de France, , p. 201 - 203 Jahresbericht ueber die Fortschritte der Chemie und Verwandter Theile Anderer Wissenschaften, , p. 207 |
|
~0%
7720-83-4 |
| 文献：Denes Georges Journal of Solid State Chemistry, 1988 , vol. 77, p. 54 - 59 |
|
~%
7720-83-4 |
| 文献：Bulletin de la Societe Chimique de France, , vol. 7, p. 198 Bulletin de la Societe Chimique de France, , vol. 7, p. 201 - 201 I: MVol.2, 21, page 291 - 293 |
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~99%
7720-83-4 |
| 文献：Troyanov, S. I.; Mazo, G. N. Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1988 , vol. 33, p. 499 - 501 Zhurnal Neorganicheskoi Khimii, 1988 , vol. 33, p. 889 - 892 |
|
~%
7720-83-4 |
| 文献：Journal of Physical Chemistry, , vol. 8, p. 500 - 504 |
| 上游产品 5 | |
|---|---|
| 下游产品 5 | |
所有的接头均为锥形，活塞使用硅酮润滑脂。在管B中投入256g（0.0534mol）的纯海绵钛，置于2段约8cm玻璃棉填充物之间。放入玻璃棉是为了使钛所处的位置不发生移动。同时也起到了使反应进行完全、减缓碘的扩散速度的作用。连接管A和管B，用电炉Ⅰ加热管B至400～425℃，管B中通入干燥的氮气，使氮气从钛上流过。氮气事先通过浓硫酸，再通过装有分子筛的塔进行干燥。管B加热至400或425℃后，将装有碘2710g（0.1068mol）的管C与管B连接起来。停止氮气流，用真空泵将全系统抽真空（1.33Pa左右）。随后将三通旋塞旋至图示的位置。用电炉Ⅱ加热至80℃使碘升华，慢慢导入反应区B中，使之与钛反应。待所有的碘从管C升华出来以后（需10～12h），将氮气通入系统，将装置冷却至室温。除去管C，用带钩的铜丝扒出玻璃棉填充物及未反应的钛（0.23g），用液氮洗涤。接着洗净管C，干燥之，再与管B连接。将管B从与A相接处摘下，保持垂直，在此期间，将图示的暗红褐色的环状产物用刮勺迅速刮掉，立即加以密封。
图IV-6 四碘化钛的制备装置
1—去真空系统；2—液氮阱；3—玻璃棉；4—安全汞封
精制产物采用如图所示装置。首先洗净管A及管B，干燥后，往B中填塞干燥的玻璃棉后，再连接起来，产物装入管C中，将管C与管B连接起来。将系统抽真空，并保持抽真空的状态。使两个电炉相距约15cm。将电炉Ⅰ加热至80℃，将电炉Ⅱ加热至130～140℃。连续升华12～16h，使粗产品四碘化钛从管C全部升华出来。精制品在两个电炉之间的地方结晶析出。主要杂质碘可在管A及液氮阱内结晶。在管C中残留的褐色残余物甚微，可忽略不计。必要时，还可将B管进一步放入电炉Ⅱ中，再次进行精制。冷却后导入氮气，摘下管C，除去玻璃棉填充物。将带有氮气导入支管及活塞的干燥烧瓶安装在管B上，通过管B将氮气导入烧瓶中。接着，将支管与干燥氮气发生器连接起来，使氮气流以反方向导入，即使氮气能经支管通过烧瓶而导入反应管中。将管B与管A分开，将生成物刮落于烧瓶中。摘下管B，将烧瓶加塞。收量为25.0g。
图IV-7 四碘化钛的精制装置
1—经液氮阱与抽真空系统连接；2—精制后的TiI4；3—粗TiI4
