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乙酸炔丙酯

乙酸炔丙酯名称

[ CAS 号 ]:
627-09-8

[ 中文名 ]:
乙酸炔丙酯

[ 英文名 ]:
Propargyl acetate

[中文别名 ]:

[英文别名 ]:

prop-2-ynyl acetate
MFCD00041601

乙酸炔丙酯物理化学性质

[ 密度 ]:
0.989

[ 沸点 ]:
27-28ºC(lit.)

[ 分子式 ]:
C₅H₆O₂

[ 分子量 ]:
98.09990

[ 闪点 ]:
91 °F

[ 精确质量 ]:
98.03680

[ PSA ]:
26.30000

[ LogP ]:
0.18270

[ 外观性状 ]:
Liquid | Clear colorless

[ 折射率 ]:
n20/D 1.417(lit.)

[ 储存条件 ]:
Flammables area

乙酸炔丙酯MSDS

详细MSDS(安全技术说明书)

乙酸炔丙酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UK5076000

CHEMICAL NAME :: 2-Propyn-1-ol, acetate

CAS REGISTRY NUMBER :: 627-09-8

BEILSTEIN REFERENCE NO. :: 1742046

LAST UPDATED :: 199612

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C5-H6-O2

MOLECULAR WEIGHT :: 98.11

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 250 mg/kg

TOXIC EFFECTS :: Behavioral - general anesthetic Behavioral - ataxia Lungs, Thorax, or Respiration - respiratory depression

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(6),55,1984

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 520 mg/kg

TOXIC EFFECTS :: Behavioral - general anesthetic Behavioral - ataxia Lungs, Thorax, or Respiration - respiratory depression

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(6),55,1984

乙酸炔丙酯安全信息

[ 符号 ]:

GHS02, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H301-H312-H332

[ 警示性声明 ]:
P280-P301 + P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)

[ 危害码 (欧洲) ]:
Xn

[ 风险声明 (欧洲) ]:
R10;R20/21/22

[ 安全声明 (欧洲) ]:
S23-S36/37

[ 危险品运输编码 ]:
UN 1992 3/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
UK5076000

[ 包装等级 ]:
II

[ 危险类别 ]:
6.1(3)

乙酸炔丙酯合成路线

详细合成路线

乙酸炔丙酯上下游产品

乙酸炔丙酯上游产品

乙酸炔丙酯下游产品

乙酸炔丙酯文献

Asymmetric synthesis of ?-hydroxy a, ß-unsaturated aldehydes via enantioselective direct addition of propargyl acetate to aldehydes El-Sayed E, et al.

Org. Lett. 3.19 , 3017-3020, (2001)

Nucleophilic reactions of propargyl acetates mediated by titanocene dichloride and magnesium Yang F, et al.

Tetrahedron Lett. 42.15 , 2839-2841, (2001)

Investigations on the ion transport mechanism in conducting polymer films Casalbore-Miceli G, et al.

Solid State Ionics 131.3 , 311-321, (2000)

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