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乙酸烯丙酯

乙酸烯丙酯用途

【用途一】
用作有机中间体
【用途二】
生产甘油的中间体。用于有机合成。

乙酸烯丙酯名称

[ CAS 号 ]:
591-87-7

[ 中文名 ]:
乙酸烯丙酯

[ 英文名 ]:
Allyl acetate

[中文别名 ]:

[英文别名 ]:

AcOCH2CH=CH2
EINECS 209-734-8
Allyl acetate
allyl p-methylbenzoate
ethylene,methyl acetate
p-Toluic acid,allyl ester
allyl 4-methyl benzoate
prop-2-enyl acetate
prop-2-en-1-yl 4-methylbenzoate
CH2=CHCH2OAc

乙酸烯丙酯物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
104.0±0.0 °C at 760 mmHg

[ 熔点 ]:
6°C

[ 分子式 ]:
C₅H₈O₂

[ 分子量 ]:
100.116

[ 闪点 ]:
6.7±0.0 °C

[ 精确质量 ]:
100.052429

[ PSA ]:
26.30000

[ LogP ]:
0.99

[ 外观性状 ]:
透明无色液体

[ 蒸汽压 ]:
31.4±0.1 mmHg at 25°C

[ 折射率 ]:
1.402

[ 储存条件 ]:
库房通风低温干燥,与氧化剂分开存放,不宜久储,以防聚合

[ 水溶解性 ]:
slightly

乙酸烯丙酯MSDS

乙酸烯丙酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AF1750000

CHEMICAL NAME :: Acetic acid, allyl ester

CAS REGISTRY NUMBER :: 591-87-7

BEILSTEIN REFERENCE NO. :: 1742050

LAST UPDATED :: 199806

DATA ITEMS CITED :: 10

MOLECULAR FORMULA :: C5-H8-O2

MOLECULAR WEIGHT :: 100.13

WISWESSER LINE NOTATION :: 1VO2U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,355,1986

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,355,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 130 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 31,60,1949

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1000 ppm/1H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60. For publisher information, see AEHLAU. Volume(issue)/page/year: 21,28,1960

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 170 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity)

REFERENCE :: FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 2,327,1964

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 1021 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 31,60,1949 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 2 mg/m3;Skin JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4803 No. of Facilities: 18 (estimated) No. of Industries: 1 No. of Occupations: 4 No. of Employees: 4280 (estimated) No. of Female Employees: 1701 (estimated)

乙酸烯丙酯安全信息

[ 符号 ]:

GHS02, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H301-H312-H319-H330

[ 警示性声明 ]:
P210-P260-P280-P284-P301 + P310-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F:Flammable;T:Toxic;

[ 风险声明 (欧洲) ]:
R11;R21;R25

[ 安全声明 (欧洲) ]:
S16-S26-S36-S45-S27

[ 危险品运输编码 ]:
UN 2333 3/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
AF1750000

[ 包装等级 ]:
II

[ 危险类别 ]:
3

[ 海关编码 ]:
29153990

乙酸烯丙酯合成路线

乙酸烯丙酯上下游产品

乙酸烯丙酯上游产品

乙酸烯丙酯下游产品

乙酸烯丙酯制备

制备方法：由丙烯、乙酸和氧在在水蒸气存在下反应，以乙酸钯为催化剂，于50-250℃进行气相反应。当反应温度在160℃时乙酸烯丙酯的空时收率为217g/L催化剂·h，乙酸转化率达99%，乙酸烯丙酯选取择性以丙烯计为94%。此反应亦可在二氧化碳存在下，以钯作催化剂（乙酸钯、乙酸镉和乙酸钾）于190℃、0.78MPa下，由丙烯、乙酸和氧制得，收率为91%。

乙酸烯丙酯海关

[ 海关编码 ]: 2915390090

[ 中文概述 ]:
2915390090. 其他乙酸酯. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2915390090. esters of acetic acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:5.5%. General tariff:30.0%