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2-溴乙烯基三甲基硅烷

2-溴乙烯基三甲基硅烷名称

[ CAS 号 ]:
41309-43-7

[ 中文名 ]:
2-溴乙烯基三甲基硅烷

[ 英文名 ]:
2-(Bromovinyl)Trimethylsilane

[中文别名 ]:

[英文别名 ]:

β-(trimethylsilyl)vinyl bromide
MFCD00040824
[(E)-2-BROMOVINYL](TRIMETHYL)SILANE
2-BROMOVINYLTRIMETHYLSILANE
2-(BROMOVINYL)TRIMETHYLSILANE
(2-BROMOVINYL)TRIMETHYLSILANE

2-溴乙烯基三甲基硅烷物理化学性质

[ 密度 ]:
1.167 g/mL at 25 °C(lit.)

[ 沸点 ]:
50-51 °C52 mm Hg(lit.)

[ 分子式 ]:
C₅H₁₁BrSi

[ 分子量 ]:
179.13000

[ 闪点 ]:
85 °F

[ 精确质量 ]:
177.98100

[ LogP ]:
2.77240

[ 折射率 ]:
n20/D 1.466(lit.)

[ 储存条件 ]:
2-8°C

2-溴乙烯基三甲基硅烷安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226-H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
10-36/37/38

[ 安全声明 (欧洲) ]:
26

[ 危险品运输编码 ]:
UN 1993 3/PG 3

[ WGK德国 ]:
3

[ 海关编码 ]:
2931900090

2-溴乙烯基三甲基硅烷合成路线

详细合成路线

2-溴乙烯基三甲基硅烷上下游产品

2-溴乙烯基三甲基硅烷上游产品

2-溴乙烯基三甲基硅烷下游产品

2-溴乙烯基三甲基硅烷海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

2-溴乙烯基三甲基硅烷文献

Palladium-Catalyzed Cross-Coupling Syntheses of Benzotriazolyl Enynes and a General Route to Enynyl Ketones and Alkynyl Ketones.

J. Org. Chem. 62(23) , 8201-8204, (1997)

A new general route to conjugated enynyl ketones was developed based on a two-step procedure. First, palladium-catalyzed cross-coupling reactions of 1-(benzotriazol-1-yl)propargyl ethyl ether (3) and ...

Ligand effects on Negishi couplings of alkenyl halides.

Org. Lett. 13(15) , 3818-21, (2011)

Negishi couplings at olefinic centers do not always occur with the anticipated maintenance of stereochemistry. The source of erosion has been traced to the ligand, and a modified method has been devel...

Spiro [2.4] hepta-1, 4, 6-triene Billups WE, et al.

J. Am. Chem. Soc. 116(14) , 6463, (1994)

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