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反-1,2-二氯乙烯

反-1,2-二氯乙烯用途

【用途一】
水质分析

反-1,2-二氯乙烯名称

[ CAS 号 ]:
156-60-5

[ 中文名 ]:
反式-1,2-二氯乙烯

[ 英文名 ]:
(E)-1,2-Dichloroethene

[中文别名 ]:

[英文别名 ]:

Acetylene dichloride, trans-
E-1,2-dichloroethene
trans-1, 2-Dichloroethene
trans-1,2-Dichloroethylene,stabilized
1,2-Dichloroethene, trans-
(E)-1,2-dichloroethylene
Ethylene, 1,2-dichloro-, (E)-
trans-dichloroethylene
Dichloroethylene, trans-
Ethene, 1,2-dichloro-, (1E)-

反-1,2-二氯乙烯物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
47.7±0.0 °C at 760 mmHg

[ 熔点 ]:
-57ºC(lit.)

[ 分子式 ]:
C₂H₂Cl₂

[ 分子量 ]:
96.943

[ 闪点 ]:
6.1±0.0 °C

[ 精确质量 ]:
95.953354

[ LogP ]:
1.75

[ 外观性状 ]:
透明液体

[ 蒸汽压 ]:
333.1±0.0 mmHg at 25°C

[ 折射率 ]:
1.453

[ 储存条件 ]:
库房通风低温干燥,轻装轻卸、与氧化剂和酸类分开存放

[ 稳定性 ]:
Incompatible with oxidizing agents, bases. Stable, but may decompose on exposure to air, moisture or light. Highly flammable.

[ 水溶解性 ]:
水溶性：实际上不溶；可溶于：苯,丙酮,醇,甲苯

反-1,2-二氯乙烯MSDS

反-1,2-二氯乙烯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: KV9400000

CHEMICAL NAME :: Ethylene, 1,2-dichloro-, (E)-

CAS REGISTRY NUMBER :: 156-60-5

BEILSTEIN REFERENCE NO. :: 1420761

LAST UPDATED :: 199803

DATA ITEMS CITED :: 24

MOLECULAR FORMULA :: C2-H2-Cl2

MOLECULAR WEIGHT :: 96.94

WISWESSER LINE NOTATION :: G1U1G -T

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Human

DOSE/DURATION :: 4800 mg/m3/10M

TOXIC EFFECTS :: Behavioral - sleep Behavioral - hallucinations, distorted perceptions

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1235 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 7411 mg/kg

TOXIC EFFECTS :: Cardiac - other changes Lungs, Thorax, or Respiration - other changes Liver - fatty liver degeneration

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2122 mg/kg

TOXIC EFFECTS :: Behavioral - altered sleep time (including change in righting reflex) Behavioral - somnolence (general depressed activity) Behavioral - ataxia

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 75 gm/m3/2H

TOXIC EFFECTS :: Behavioral - general anesthetic Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - dyspnea

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 3952 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Mammal - cat

DOSE/DURATION :: 43 gm/m3/6H

TOXIC EFFECTS :: Behavioral - general anesthetic Behavioral - convulsions or effect on seizure threshold Gastrointestinal - nausea or vomiting

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Skin and Appendages - dermatitis, irritative (after systemic exposure) Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 113 gm/kg/90D-C

TOXIC EFFECTS :: Kidney, Ureter, Bladder - changes in bladder weight

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 200 ppm/8H/16W-I

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - other changes Liver - other changes Endocrine - changes in endocrine weight (unspecified)

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

DOSE :: 6000 ppm/6H

SEX/DURATION :: female 7-16 day(s) after conception

TOXIC EFFECTS :: Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

DOSE :: 12000 ppm/6H

SEX/DURATION :: female 7-16 day(s) after conception

TOXIC EFFECTS :: Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)

MUTATION DATA

TYPE OF TEST :: Sex chromosome loss and nondisjunction

TEST SYSTEM :: Rodent - hamster Lung

DOSE/DURATION :: 6500 umol/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 182,135,1987

反-1,2-二氯乙烯安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H332-H412

[ 警示性声明 ]:
P210-P273

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)

[ 危害码 (欧洲) ]:
Xn: Harmful;F: Flammable;T: Toxic;

[ 风险声明 (欧洲) ]:
R11;R20;R52/53

[ 安全声明 (欧洲) ]:
7-16-29-61-45-36/37

[ 危险品运输编码 ]:
UN 1150 3/PG 2

[ WGK德国 ]:
2

[ RTECS号 ]:
KV9400000

[ 包装等级 ]:
II

[ 危险类别 ]:
3

[ 海关编码 ]:
2903299090

反-1,2-二氯乙烯合成路线

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反-1,2-二氯乙烯海关

[ 海关编码 ]: 2903299090

[ 中文概述 ]:
HS: 2903299090. 其他无环烃的不饱和氯化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2903299090 other unsaturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

反-1,2-二氯乙烯文献

Calculating virtual log P in the alkane/water system (log P(N)(alk)) and its derived parameters deltalog P(N)(oct-alk) and log D(pH)(alk).

J. Med. Chem. 48 , 3269-79, (2005)

Growing interest in the use of both the logarithm of the partition coefficient of the neutral species in the alkane/water system (log P(N)(alk)) and the difference between log P(N)(oct) (the logarithm...

QSPR modeling of octanol/water partition coefficient for vitamins by optimal descriptors calculated with SMILES.

Eur. J. Med. Chem. 43 , 714-40, (2008)

Simplified molecular input line entry system (SMILES) has been utilized in constructing quantitative structure-property relationships (QSPR) for octanol/water partition coefficient of vitamins and org...

Demonstration of compound-specific isotope analysis of hydrogen isotope ratios in chlorinated ethenes.

Environ. Sci. Technol. 47(3) , 1461-7, (2013)

High-temperature pyrolysis conversion of organic analytes to H(2) in hydrogen isotope ratio compound-specific isotope analysis (CSIA) is unsuitable for chlorinated compounds such as trichloroethene (T...

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