N,N'-(4,4'-亚甲基二苯基)双马来酰亚胺
用途
用途二:可用于生产电器绝缘材料、耐磨材料、增强塑料添加剂、橡胶交联剂、航空结构材料、航天结构材料、功能材料等.用于制备电器绝缘材料、耐磨材料、增强塑料添加剂、砂轮粘结剂等。
用途三:BMI 作为双马树脂基体,具有突出的特性:抗热性、抗氧化性、抗辐射性。广泛应用于电力、航空、航天、计算机、通讯、汽车、铁路、建筑等工业领域。
名称
[ CAS 号 ]:
13676-54-5
[ 中文名 ]:
4,4'-双马来酰亚胺基二苯甲烷
[ 英文名 ]:
Bismaleimide
[中文别名 ]:
[英文别名 ]:
- bismaleimides
- mb-3000
- matrimid5258
- 1,1'-(methylenedi-4,1-phenylene)bismaleimide
- 4,4'-Bismaleimidodiphenylmethane
- 4,4'-Methylenebis(N-phenylmaleimide)
- MFCD00005507
- Bis(4-maleimidophenyl)methane
- N,N'-(methylenedi-p-phenylene)dimaleimide
- MB-3000H
物理化学性质
[ 密度 ]:
1.4±0.1 g/cm3
[ 沸点 ]:
584.9±43.0 °C at 760 mmHg
[ 熔点 ]:
156-158 °C(lit.)
[ 分子式 ]:
C21H14N2O4
[ 分子量 ]:
358.347
[ 闪点 ]:
278.3±20.5 °C
[ 精确质量 ]:
358.095367
[ PSA ]:
74.76000
[ LogP ]:
1.95
[ 外观性状 ]:
黄色晶体
[ 蒸汽压 ]:
0.0±1.6 mmHg at 25°C
[ 折射率 ]:
1.690
[ 储存条件 ]:
库房通风低温干燥
MSDS
毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- ON5670000
- CHEMICAL NAME :
- Maleimide, N,N'-(methylenedi-p-phenylene)di-
- CAS REGISTRY NUMBER :
- 13676-54-5
- BEILSTEIN REFERENCE NO. :
- 0333986
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 7
- MOLECULAR FORMULA :
- C21-H14-N2-O4
- MOLECULAR WEIGHT :
- 358.37
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >5 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 350 mg/m3/4H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- >5 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
MUTATION DATA
- TYPE OF TEST :
- Cytogenetic analysis
- TEST SYSTEM :
- Rodent - hamster Ovary
- DOSE/DURATION :
- 2500 ug/L
- REFERENCE :
- EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-0491-1069 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X1310 No. of Facilities: 10 (estimated) No. of Industries: 2 No. of Occupations: 1 No. of Employees: 21 (estimated) No. of Female Employees: 7 (estimated)
安全信息
[ 符号 ]:
GHS06
[ 信号词 ]:
Danger
[ 危害声明 ]:
H315-H319-H330-H335
[ 警示性声明 ]:
P260-P284-P305 + P351 + P338-P310
[ 个人防护装备 ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
[ 危害码 (欧洲) ]:
T:Toxic
[ 风险声明 (欧洲) ]:
R23;R36/37/38
[ 安全声明 (欧洲) ]:
S26-S45-S37/39
[ 危险品运输编码 ]:
UN 2811 6.1/PG 2
[ WGK德国 ]:
2
[ RTECS号 ]:
ON5670000
[ 包装等级 ]:
III
[ 危险类别 ]:
6.1
合成路线
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文献
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To date, many different chemotherapeutic agents have been widely used as common treatments for oral cancers. However, their therapeutic effects have been disappointing, and these agents may have unwan...
Down-regulation of Akt by methanol extracts of Impatiens balsamina L. promotes apoptosis in human oral squamous cell carcinoma cell lines.J. Oral. Pathol. Med. 44 , 420-8, (2015)
The apoptotic activity of methanol extracts of Impatiens balsamina L. (MEIB) and related mechanisms in human oral squamous cell carcinoma (OSCC) cells have been systematically investigated.The effects...
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