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2-苄基吡啶

2-苄基吡啶用途

【用途一】
用于有机合成

2-苄基吡啶名称

[ CAS 号 ]:
101-82-6

[ 中文名 ]:
2-苄基吡啶

[ 英文名 ]:
2-Benzylpyridine

[中文别名 ]:

2-(苯甲基)吡啶

[英文别名 ]:

2-Benzyl-pyridine
2-PHENYLPYRIDYLMETHANE
2-benzyl-pyridin
2-benzylpridine
Pyridine, 2-benzyl-
Pyridine, 2- (phenylmethyl)-
2-Benzylpyridine
MFCD00006352
benzyl-2-pyridine
2-(PHENYLMETHYL)PYRIDINE

2-苄基吡啶物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
276.0±0.0 °C at 760 mmHg

[ 熔点 ]:
8-10 °C(lit.)

[ 分子式 ]:
C₁₂H₁₁N

[ 分子量 ]:
169.222

[ 闪点 ]:
125.0±0.0 °C

[ 精确质量 ]:
169.089142

[ PSA ]:
12.89000

[ LogP ]:
2.71

[ 外观性状 ]:
透明暗棕色液体

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.576

[ 储存条件 ]:
室温，密封

[ 水溶解性 ]:
insoluble

2-苄基吡啶MSDS

2-苄基吡啶毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: US2620000

CHEMICAL NAME :: Pyridine, 2-benzyl-

CAS REGISTRY NUMBER :: 101-82-6

BEILSTEIN REFERENCE NO. :: 0115875

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C12-H11-N

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1500 mg/kg

TOXIC EFFECTS :: Behavioral - tremor Behavioral - convulsions or effect on seizure threshold Cardiac - pulse rate increase, without fall in BP

REFERENCE :: AEPPAE Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. (Berlin, Ger.) V.110-253, 1925-66. For publisher information, see NSAPCC. Volume(issue)/page/year: 227,129,1955

2-苄基吡啶安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H319

[ 警示性声明 ]:
P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R22;R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39

[ 危险品运输编码 ]:
2810

[ WGK德国 ]:
3

[ RTECS号 ]:
US2620000

[ 包装等级 ]:
I; II; III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
29333999

2-苄基吡啶合成路线

2-苄基吡啶上下游产品

2-苄基吡啶上游产品

2-苄基吡啶下游产品

2-苄基吡啶海关

[ 海关编码 ]: 2933399090

[ 中文概述 ]:
2933399090. 其他结构含非稠合吡啶环的化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

2-苄基吡啶文献

Copper-catalyzed α-methylenation of benzylpyridines using dimethylacetamide as one-carbon source.

Org. Lett. 16(7) , 2050-3, (2014)

The direct α-methylenation of benzylpyridines was achieved using N,N-dimethylacetamide (DMA) as a one-carbon source under copper catalysis. An intermediary species was detected at an early stage, and ...

Ruthenium(II) complexes of 2-benzoylpyridine-derived thiosemicarbazones with cytotoxic activity against human tumor cell lines.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 69(4) , 1073-6, (2008)

Reaction of [RuCl(3)(dppb)H(2)O] (dppb=1,4 bis(diphenylphospine)butane) with 2-benzoylpyridine thiosemicarbazone (H2Bz4DH) and its N(4)-methyl (H2Bz4M) and N(4)-phehyl (H2Bz4Ph) derivatives gave [RuCl...

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