Acyl Exchanges between Esters and 1, 3-Diketones and β-Keto-esters

SM McElvain, KH Weber

文献索引：McElvain; Weber Journal of the American Chemical Society, 1941 , vol. 63, p. 2192,2193

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被引用次数: 8

摘要

In a study of the reaction of alkyl benzoates with sodium alkoxides 'it was found that the isopropyl ester yielded, among other products, benzoylacetone and dibenzoylmethane. The formation of these 1, 3-diketones was thought to be the result of three consecutive reactions, viz.,(a) a reverse Tischtschenko reaction through which the isopropyl benzoate under the influence of the alkoxide broke into benzaldehyde and acetone,(b) the condensation of ...