Heteroacylsilanes: synthesis and synthetic potentialities of new nucleophilic acylation agents

…, A Degl'Innocenti, S Chimichi, M Fiorenza…

文献索引：Ricci, ALfredo; Degl'Innocenti, Alessandro; Chimichi, Stefano; Fiorenza, Mariella; Rossini, Gabriele; bestmann, Hans Jurgen Journal of Organic Chemistry, 1985 , vol. 50, # 1 p. 130 - 133

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被引用次数: 57

摘要

and on the Corey-Seebach procedure2 for the synthesis of 2-furoyl-(la), 2-thenoyl-(lb), and (2-N-methylpyrroy1)-trimethylsilane (l~).~ However, the transition metal catalyst based procedure of forming C-Si bonds, first described by Atwell and Bokerman4 and further developed by other authors: proved (Scheme 1) to be suitable for the synthesis of la-c, starting from the corresponding acyl chlorides.