Vanadium (V) peroxy complexes. New versatile biomimetic reagents for epoxidation of olefins and hydroxylation of alkanes and aromatic hydrocarbons

H Mimoun, L Saussine, E Daire, M Postel…

文献索引：Mimoun; Saussine; Daire; Postel; Fischer; Weiss Journal of the American Chemical Society, 1983 , vol. 105, # 10 p. 3101 - 3110

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被引用次数: 426

摘要

Abstract: Novel covalent vanadium (V) oxo peroxo complexes of general formula VO (O,)(ON) LL'[type I, 0-N= pyridine-2-carboxylate (Pic), pyrazine-2-carboxylate; L, L'= HzO, MeOH, monodentate or bidentate basic ligands] and anionic complexes with the general formula [VO (O,)(Pic),]-A+ L [type 11, A+= H+, PPh4+; L= H20, hexamethylphosphoric triamide (HMFT)] were synthesized and characterized by physicochemical methods and X ...