The synthesis, redox properties, and ligand binding of heterobinuclear transition-metal macrocyclic ligand complexes. Measurement of an apparent delocalization …
…, TJ Smith, CA Hamann, WR Thies…
文献索引：Gagne, R. R.; Spiro, C. L.; Smith, T. J.; Hamann, C. A.; Thies, W. R.; Shiemke, A. K. Journal of the American Chemical Society, 1981 , vol. 103, # 14 p. 4073 - 4081
Abstract: A series of binuclear complexes MAr1Mi1L2+ have been synthesized and characterized. The binucleating macrocyclic ligand L2-is a symmetric Schiff base derived by condensing 2 equiv of 2, 6-diformyl-4-methylphenol with 2 equiv of 1, 3-diaminopropane, resulting in two identical N202 coordination sites. In all cases, M,(II)= Cu (I1) while MB was varied across the series MB (I1)= Mn (II), Fe (II), Co (II), Ni (II), Cu (II), and Zn (I1). The ...
