Exchange coupling in a bis (heterodinuclear)[Cu II Ni II] 2 and a linear heterotrinuclear complex Co III Cu II Ni II. Synthesis, structures and properties
CN Verani, E Rentschler, T Weyhermüller…
文献索引：Verani, Claudio Nazari; Rentschler, Eva; Weyhermueller, Thomas; Bill, Eckhard; Chaudhuri, Phalguni Journal of the Chemical Society, Dalton Transactions, 2000 , # 3 p. 251 - 258
Two heterometallic complexes [{CuII (HLOX) NiII (N3)} 2] and [(tmtacn) CoIII (μ-OH) CuII (LOX) NiII (OH2) 2][ClO4] 2 (tmtacn= 1, 4, 7-trimethyl-1, 4, 7-triazacyclononane) containing the same [CuIINiII] core embedded in an unsymmetrical dicompartmental imine-oxime ligand H4LOX have been synthesized and characterized. Their crystal structures show that the CuII resides at the N (oxime) 2O (phenolate) 2 site and assumes a planar geometry. ...
[Gagne, R. R.; Spiro, C. L.; Smith, T. J.; Hamann, C. A.; Thies, W. R.; Shiemke, A. K. Journal of the American Chemical Society, 1981 , vol. 103, # 14 p. 4073 - 4081]
