Controlled synthesis and reversible oxidation of a thiolate-bridged macrocyclic dinickel (II) complex

S Brooker, PD Croucher, FM Roxburgh

文献索引：Brooker, Sally; Croucher, Paul D.; Roxburgh, Fiona M. Journal of the Chemical Society - Dalton Transactions, 1996 , # 14 p. 3031 - 3037

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被引用次数: 30

摘要

The synthesis of S-(2, 6-Diformyl-4-methylphenyl) dimethylthiocarbamate, a valuable thiolate-containing ligand precursor, is reported in detail for the first time. This precursor has considerable potential in biosite modelling studies. A macrocycle L and a related acyclic ligand L′ have been prepared, as complexes, from the precursor and 1, 3-diaminopropane. The macrocycle was successfully templated by both zinc (II) and nickel (II) ions yielding [ ...