Synthesis of fused ring heterocycles from aromatic amines with hydroximoyl chlorides

…, C Párkányi, SM Rashid, WD Lloyd

文献索引：Abdelhamid, Abdou O.; Parkanyi, Cyril; Rashid, S. M. Khaledur; Lloyd, Winston D. Journal of Heterocyclic Chemistry, 1988 , vol. 25, p. 403 - 405

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被引用次数: 12

摘要

Abstract Substituted 2-arylbenzimidazoles, 2-arylbenzoxazoles and 2-arylbenzothiazoles were obtained in good yield by the reaction of hydroximoyl chlorides with ortho-substituted aromatic amines. The benzo moiety of the benzimidazoles was shown by nmr to be symmetrical, indicating that the NH group proton of the imidazole ring is exchanging with the water protons in the DMSO-d 6 solvent.