Organometallics

Chemistry of metal hydrides. 25. Reactions of trans-[PtH2 (PCy3) 2] with carbon monoxide and other. pi. acids

GK Anderson, HC Clark, JA Davies

文献索引：Anderson, Gordon K.; Clark, Howard C.; Davies, Julian A. Organometallics, 1982 , vol. 1, p. 550 - 553

被引用次数: 13

摘要

In many homogeneous catalytic systems, one of the key steps is believed to be the insertion of unsaturated, organic molecules into metal-hydrogen bonds.'Within this context, reactions of hydridoplatinum (I1) complexes, truns-[PtHX (PRJ2], with olefinsM and acetylenes-have been extensively studied. Four-coordinate cationic complexes, formed by anion displacement, and/or five-coordinate intermediates have been proposed3 during the ...

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