Catalytic hydrogenation of aryl phosphines by niobium aryloxide compounds: high yield and efficient synthesis of cyclohexyl phosphine ligands

SY Joyce, IP Rothwell

文献索引：Yu, Joyce S.; Rothwell, Ian P. Journal of the Chemical Society, Chemical Communications, 1992 , # 8 p. 632 - 633

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被引用次数: 1

摘要

There has been considerable recent research interest into the chemistry of transition metal complexes containing bi- and tri-dentate phosphine ligands containing electron-donating substituents at phosphorus. 1 We communicate here our development of a new process for the catalytic hydrogenation of aryl phosphines by a niobium aryloxide compound.2 The process provides an efficient method for the synthesis of more basic cyclohexyl phosphine ligands from their aromatic ...