Photochemistry of alkyl halides. 11. Competing reaction via carbene and carbocationic intermediates

PJ Kropp, JA Sawyer, JJ Snyder

文献索引：Kropp, Paul J.; Sawyer, Joy A.; Snyder, John J. Journal of Organic Chemistry, 1984 , vol. 49, # 9 p. 1583 - 1589

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被引用次数: 13

摘要

Isotopic analysis of the unsaturated products 6 and 15 resulting from irradiation of the labeled iodides 1-1, 1-d2, 1-2, 2-d2, and 13-1-d has revealed that they are formed substantially, but not exclusively, via a elimination. The unsaturated products thus arise via competiflg pathways involving carbene intermediates as well as the previously recognized radical and carbocationic intermediates. Irradiation of iodide 22 in methanol-d afforded ...