Tetrahedron letters

Reactivity of RCu, BF3 and R2CuLi, BF3 towards the ether linkage. Epoxides, acetals and orthoformates

A Ghribi, A Alexakis, JF Normant

文献索引：Ghribi, A.; Alexakis, A.; Normant, J. F. Tetrahedron Letters, 1984 , vol. 25, # 29 p. 3075 - 3078

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被引用次数: 65

摘要

Abstract The association of BF 3 to organocopper and cuprate reagents increases dramatically their reactivity towards epoxides. The same reagents cleave acetals to afford the product of substitution of one alkoxy group, whereas orthoformates lead to acetals under conditions where no further attack occurs.