Journal of the American Chemical Society

The Action of the Halogen Hydrins and of Ethylene Oxide on the Thioureas

JF Olin, FB Dains

文献索引：Olin; Dains Journal of the American Chemical Society, 1930 , vol. 52, p. 3323

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被引用次数: 13

摘要

The basis of this investigation was the observation that thiocarbanilide could be desulfurized with ethylene chlorohydrin, as follows. The thiourea was boiled with the chlorohydrin, giving a partial yield of diphenylurea which could be increased to 60% by heating the reaction product with alcoholic potassium hydroxide, thus completing the hydrolysis of the intermediate thio ether, C~ HSNHC (NC~ H~) SCH~ CH~ OH. In order to throw more light ...