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Metal–ligand cooperation in the catalytic dehydrogenative coupling (DHC) of polyalcohols to carboxylic acid derivatives

M Trincado, K Kühlein…

文献索引:Trincado, Monica; Kuehlein, Klaus; Gruetzmacher, Hansjoerg Chemistry - A European Journal, 2011 , vol. 17, # 42 p. 11905 - 11913

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被引用次数: 30

摘要

Abstract Several polyols, which are easily available from sugars through biochemical conversion or hydrogenolytic cleavage, are directly converted into carboxylic acids and amides. This efficient dehydrogenative coupling process, catalyzed by a rhodium (I) diolefin amido complex, is an attractive approach for the production of organic fine chemicals from renewable resources. This method tolerates the presence of several hydroxy groups and ...