Organometallics

A Stabilized Triarylbismuthane Imide: Synthesis and First X-ray Structure Analysis

T Ikegami, H Suzuki

文献索引：Ikegami, Tohru; Suzuki, Hitomi Organometallics, 1998 , vol. 17, # 6 p. 1013 - 1017

全文：HTML全文

被引用次数: 12

摘要

Treatment of dichloride 6 with TfNH2 in the presence of t-BuOK gave the moisture- insensitive triarylbismuthane imide 7 with an oxazoline group at a position ortho to the carbon bearing the bismuth atom. The first X-ray structure analysis of bismuthane imide has been carried out for compound 7, revealing that the bismuth center has a distorted-trigonal- bipyramidal geometry and the Bi-N bond possesses a polarized Bi+-N-bond nature rather ...