Organometallics

Synthesis, halogenolysis, and crystal structure of hypervalent organobismuth compounds (10-Bi-5)

X Chen, K Ohdoi, Y Yamamoto, K Akiba

文献索引：Chen, Xiang; Ohdoi, Keisuke; Yamamoto, Yohsuke; Akiba, Kin-ya Organometallics, 1993 , vol. 12, p. 1857 - 1864

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被引用次数: 20

摘要

Recently Barton et al. reported a series of phenylations utilizing pentavalent Bi-aryl compounds including Bi-(C6H5) 5, indicating the uniqueness of the weak bonding of hypervalent bismuth compounds. l However, systematic studies for the preparation, structure, and reactivity of 10-Bi-5 type hypervalent organobismuth compounds have not been carried out mostly because of the instability of those compounds. 2 Especially, the ...