Synthesis, structure and reactions of μ-oxobis (arenesulfonatotriarylbismuth)

…, TK Ivanenko, II Pavlushkina, AV Gerasimenko…

文献索引：Sharutin; Egorova; Sharutina; Ivanenko; Pavlushkina; Gerasimenko; Pushilin Russian Journal of General Chemistry, 2004 , vol. 74, # 9 p. 1359 - 1364

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被引用次数: 1

摘要

Abstract Hydrolysis of triarylbismuth bis (arenesulfonates) in acetone gives bismuth derivatives of the general formula [Ar 3 Bi (OSO 2 Ar')] 2 O (Ar= Ph, p-Tol; Ar'= Ph, C 6 H 4 Me-4, C 6 H 3 Me 2-2, 4, C 6 H 3 Me 2-3, 4). The structure of μ-oxobis [(3, 4- dimethylbenzenesulfonato) triphenylbismuth] was established by means of X-ray diffraction. The molecule has a linear centrosymmetric structure with the bridging oxygen atom in the ...